Volatile complexes of Nb(IV) with new sterically hindered β-diketones

被引：0

作者：

Kandybin, MV ^{[1
]}

Belaya, SV

Malkova, VI

Nadolinnyi, VA

Semyannikov, PP

Igumenov, IK

Zanina, AS

Shergina, SI

Sokolov, IE

机构：

[1] Russian Acad Sci, Inst Inorgan Chem, Siberian Div, Novosibirsk, Russia

[2] Russian Acad Sci, Inst Chem Kinet & Combust, Siberian Div, Novosibirsk, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 1999年 / 69卷 / 06期

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D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reactions of niobium tetraiodide with sterically hindered beta-diketones in the presence of diethylamine gave eight-coordinate Nb(IV) complexes Nb(beta-diket)(4). The thermal stability of the complexes at atmospheric pressure and in a vacuum and the nature of the hydrolysis and oxidation products were studied. The possibility of using the complexes as precursors for preparing Nb(IV) oxide layers was examined.

引用

页码：866 / 875

页数：10

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