A study of pyrolysis and pyrolysis products of flame-retardant cotton fabrics by DSC, TGA, and PY-GC-MS

被引：221

作者：

Zhu, P ^{[1
]}

Sui, SY

Wang, B

Sun, K

Sun, G

机构：

[1] Qingdao Univ, Coll Chem Engn, Qingdao 266071, Peoples R China

[2] DongHua Univ, Shanghai 200051, Peoples R China

[3] Univ Calif Davis, Div Text & Clothings, Davis, CA 95616 USA

来源：

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS | 2004年 / 71卷 / 02期

关键词：

cotton fibers; flame-retardant finish; pyrolysis; pyrolysis products;

D O I：

10.1016/j.jaap.2003.09.005

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Study of thermal decompositions of cotton and flame-retardant cotton fabrics can assist understanding of fire-resistant functions of the materials. In this research, differential scanning calorimeter (DSC), thermogravimetric analysis (TGA) and pyrolysis-gas chromatography-mass spectroscopy (PY-GC-MS) were employed to investigate decomposition processes and decomposed products of flame-retardant treated (using an organo-phosphorus compound) and untreated cotton fibers in the pyrolysis. The thermal decomposition temperatures, weight losses and potential reactions of the pyrolysis as well as resulted fragments, were analyzed. The results are helpful in understanding of mechanisms of flame-retardant cotton fabrics. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：645 / 655

页数：11

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