Synthesis of sulfonated poly(phthalazinone ether sulfone)s by direct polymerization

被引：73
|
作者：
Xiao, GY
Sun, GM
Yan, DY
Zhu, PF
Tao, P
机构：
[1] Shanghai Jiao Tong Univ, Sch Chem & Chem Technol, Shanghai 200240, Peoples R China
[2] Shanghai Jiao Tong Univ, Instrumental Anal Ctr, Shanghai 200240, Peoples R China
来源：
POLYMER | 2002年 / 43卷 / 19期
关键词：
sulfonation; poly(phthalazinone ether sulfone)s; direct polycondensation;
D O I：
10.1016/S0032-3861(02)00365-8
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Sulfonated poly(phthalazinone ether sulfone)s with high molecular weight were directly prepared by polycondensation of 4-(4-hydroxyphenyl) phthalazinone with various ratios of disodium 5.5'-sulfonylbis(2-fluoro-benzenesulfonate) to 4-fluorophenyl sulfone. The resulting ionomers with high IEC showed low swelling. The low swelling originates from intermolecular hydrogen bonds, which is confirmed by variable temperature IR spectroscopy. The membranes show very good perspectives in PEMFC applications. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：5335 / 5339
页数：5
相关论文
共 50 条
  • [1] Synthesis of sulfonated poly(arylene ether sulfone)s via direct polymerization
    Wang, F.
    Ji, Q.
    Harrison, W.
    Mecham, J.
    Formato, R.
    Kovar, R.
    Osenar, P.
    McGrath, J.E.
    2000, ACS, Washington, DC, United States (41):
  • [2] Synthesis of sulfonated poly(arylene ether sulfone)s via direct polymerization.
    Wang, F
    Ji, Q
    Harrison, W
    Mecham, J
    McGrath, JE
    Formato, R
    Kovar, R
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2000, 219 : U378 - U378
  • [3] Synthesis of sulfonated poly(arylene ether phosphine oxide sulfone)s via direct polymerization.
    Wang, F
    Mecham, J
    Harrison, W
    Hickner, M
    Kim, Y
    McGrath, JE
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2001, 221 : U435 - U435
  • [4] Synthesis and characteristics of sulfonated poly(phthalazinone ether sulfone ketone) (SPPESK) for direct methanol fuel cell (DMFC)
    Gu, Shuang
    He, Gaohong
    Wu, Xuemei
    Li, Chennan
    Liu, Hongjing
    Lin, Chang
    Li, Xiangcun
    JOURNAL OF MEMBRANE SCIENCE, 2006, 281 (1-2) : 121 - 129
  • [5] Synthesis and characterization of sulfonated poly(phthalazinone ether sulfone ketone) for ultrafiltration and nanofiltration membranes
    Dai, Y
    Jian, XG
    Liu, XM
    Guiver, MD
    JOURNAL OF APPLIED POLYMER SCIENCE, 2001, 79 (09) : 1685 - 1692
  • [6] Catalytic activity of sulfonated poly (phthalazinone ether sulfone ketone) resin
    An, ZJ
    Zhou, P
    Jian, XG
    Cai, TX
    ACTA PHYSICO-CHIMICA SINICA, 2003, 19 (01) : 1 - 3
  • [7] Preparation and properties of sulfonated poly (phthalazinone ether sulfone ketone)/sulfonated poly (ether ether ketone) blend proton exchange membrane
    He, G. (hgaohong@dlut.edu.cn), 1600, Sichuan University (28):
  • [8] Synthesis of highly sulfonated poly(arylene ether sulfone) random (statistical) copolymers via direct polymerization
    Wang, F
    Hickner, M
    Ji, Q
    Harrison, W
    Mecham, J
    Zawodzinski, TA
    McGrath, JE
    MACROMOLECULAR SYMPOSIA, 2001, 175 : 387 - 395
  • [9] Synthesis of highly sulfonated poly(arylene ether sulfone) random (statistical) copolymers via direct polymerization
    Wang, Feng
    Hickner, Michael
    Ji, Qing
    Harrison, William
    Mecham, Jeffrey
    Zawodzinski, Thomas A.
    McGrath, James E.
    Macromolecular Symposia, 2001, 175 : 387 - 396
  • [10] Low methanol permeable sulfonated poly(phthalazinone ether sulfone) membranes for DMFCs
    Fang, Jun
    Shen, Pei Kang
    Liu, Qing Lin
    JOURNAL OF MEMBRANE SCIENCE, 2007, 293 (1-2) : 94 - 99
12345