The potential of methylsiloxanes as solvents for synthetic chemistry applications

被引：16

作者：

Ab Rani, Mohd Azri ^{[1
]}

Borduas, Nadine ^{[1
]}

Colquhoun, Victoria ^{[1
]}

Hanley, Robert ^{[1
]}

Johnson, Henry ^{[1
]}

Larger, Solene ^{[1
]}

Lickiss, Paul D. ^{[1
]}

Llopis-Mestre, Veronica ^{[1
]}

Luu, Selina ^{[1
]}

Mogstad, Martin ^{[1
]}

Oczipka, Philipp ^{[1
]}

Sherwood, James R. ^{[1
]}

Welton, Tom ^{[1
]}

Xing, Jun-Yi ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England

来源：

GREEN CHEMISTRY | 2014年 / 16卷 / 03期

基金：

英国工程与自然科学研究理事会;

关键词：

SOLVATOCHROMIC COMPARISON METHOD; PHASE-TRANSFER CATALYSIS; SOLVATION ENERGY RELATIONSHIPS; ALKALI-METAL COMPLEXES; IN-VIVO EVALUATION; IONIC LIQUIDS; REPRODUCTIVE TOXICITY; CARBONYL-COMPOUNDS; OH RADICALS; PI-STAR;

D O I：

10.1039/c3gc42036a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The potential use of volatile methylsiloxanes (VMSs) as solvents for chemicals synthesis has been explored. Assessment of the environmental impact of these VMS solvents is made and found to be significantly lower than those of the non-polar organic solvents that they have the potential to replace. The polarities of the VMSs, as expressed by empirical polarity measurements, and miscibilities with other liquids are found to be similar to those of alkane solvents. Finally, some uses of VMSs as solvents for both organic and inorganic transformations are described. The VMSs provide environmentally more sustainable (greener) alternatives to the nonpolar solvents that they have the potential to replace.

引用

页码：1282 / 1296

页数：15

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