Metal-Containing Carbon Nitride Compounds: A New Functional Organic-Metal Hybrid Material

被引：1233

作者：

Wang, Xinchen ^{[1
,2
]}

Chen, Xiufang ^{[1
]}

Thomas, Arne ^{[2
]}

Fu, Xianzhi ^{[1
]}

Antonietti, Markus ^{[2
]}

机构：

[1] Fuzhou Univ, State Key Lab Breeding Base Photocatalysis, Res Inst Photocatalysis, Fuzhou 350002, Peoples R China

[2] Max Planck Inst Colloids & Interfaces, Dept Colloid Chem, D-14476 Potsdam, Germany

来源：

ADVANCED MATERIALS | 2009年 / 21卷 / 16期

关键词：

VISIBLE-LIGHT; IRON; EPOXIDATION; CYTOCHROME-P450; HYDROXYLATION; DEGRADATION; IRRADIATION; POLLUTANTS; COMPLEXES; OXIDATION;

D O I：

10.1002/adma.200802627

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The electronic and optical functions of polymeric C3N4 can be easily modified by the inclusion of metal species such as Fe in its structure. The metal species lowers the bandgap and expands the light absorption of the material further into the visible region of the electromagnetic spectrum, while keeping a sufficient overpotential for carrying out oxidation reactions.

引用

页码：1609 / +

页数：5

共 36 条

[1]

[Anonymous], 1992, Handbook of X-Ray Photoelectron Spectroscopy: A Reference Book of Standard Spectra for Identification and Interpretation of XPS Data 1992

[2] Catalytic epoxidation and 1,2-dihydroxylation of olefins with bispidine-iron(II)/H2O2 systems [J].