A porphyrin nanotube:: Size-selective inclusion of tetranuclear molybdenum-oxo clusters

被引：71

作者：

Harada, R ^{[1
]}

Matsuda, Y ^{[1
]}

Ökawa, H ^{[1
]}

Kojima, T ^{[1
]}

机构：

[1] Kyushu Univ, Dept Chem, Fac Sci, Higashi Ku, Fukuoka 8128581, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 14期

关键词：

inclusion compounds; molybdenum; nanotubes; noncovalent interactions; self-assembly;

D O I：

10.1002/anie.200353325

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mo takes the tube: A saddle-distorted Mov-porphyrin complex forms a tubular assembly through intermolecular π-π interactions, which has an internal diameter of 1 nm (see picture). Within such tubes, tetranuclear Mo VI-oxo clusters could be size-selectively included through intermolecular hydrogen-bonding interactions.

引用

页码：1825 / 1828

页数：4

共 37 条

[1] Multiconformational surfaces in porphyrins: Previews into excited-state landscapes [J].

Barkigia, KM ;

Nurco, DJ ;

Renner, MW ;

Melamed, D ;

Smith, KM ;

Fajer, J .

JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (01) :322-326

[2]

Biradha K, 2000, ADV SUPR CH, V6, P1

[3]

Bong D.T., 2001, ANGEW CHEM, V113, P1016

[4]

Bong DT, 2001, ANGEW CHEM INT EDIT, V40, P988, DOI 10.1002/1521-3773(20010316)40:6<988::AID-ANIE9880>3.3.CO

[5]

2-E

[6] Designing supramolecular porphyrin arrays that self-organize into nanoscale optical and magnetic materials [J].

Drain, CM ;

Batteas, JD ;

Flynn, GW ;

Milic, T ;

Chi, N ;

Yablon, DG ;

Sommers, H .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2002, 99 :6498-6502

[7] Entropically driven self-assembly of multichannel rosette nanotubes [J].

Fenniri, H ;

Deng, BL ;

Ribbe, AE ;

Hallenga, K ;

Jacob, J ;

Thiyagarajan, P .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2002, 99 :6487-6492

[8] Helical rosette nanotubes: Design, self-assembly, and characterization [J].

Fenniri, H ;

Packiarajan, M ;

Vidale, KL ;

Sherman, DM ;

Hallenga, K ;

Wood, KV ;

Stowell, JG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (16) :3854-3855

[9] Synthesis and properties of rhodium(III) porphyrin cyclic tetramer and cofacial dimer [J].

Fukushima, K ;

Funatsu, K ;

Ichimura, A ;

Sasaki, Y ;

Suzuki, M ;

Fujihara, T ;

Tsuge, K ;

Imamura, T .

INORGANIC CHEMISTRY, 2003, 42 (10) :3187-3193

[10] Main-group element, organic, and organometallic derivatives of polyoxometalates [J].

Gouzerh, P ;

Proust, A .

CHEMICAL REVIEWS, 1998, 98 (01) :77-111

← 1 2 3 4 →