Effect assessment of chelators on bioaccessible and total chromium extraction in soils polluted by chromite processing wastes

Solid wastes from chromium-processing facilities, when used as fill material, have generated chromium point source contamination of soils and groundwaters, that remains after decades in many urban and peri urban areas all over the world, causing environmental impacts that need to be addressed in a sustainable economic, social and environmental way. Representative surface soil samples, from a polluted area affected by chromite wastes burials, were used to carry on a feasibility study on Phytoextraction applicability, and chelating agents' selection to reduce environmental risks, considering chromium bioaccessible forms reduction as an objective. Tests for natural (only vegetation), and induced phytoextraction (plants thorn chelating agents) applicability were performed at greenhouse facilities under controlled conditions at two rounds. Natural phytoextraction tests, using first wheat and then corn plants, allowed to observe a low but significant 4,8% reduction in soil chromium. At induced phytoextraction trials, when comparing the action of the different chelating agents versus a blank on final soil chromium concentration, the results were not so conclusive globally (0,5% less soil chromium in trials in which the first crop was wheat followed by corn, and 2% in trials in which the first and the second crop was corn). In each group, the most "effective" chelating agent differed: EDDS for the first set, MGDA for the second one.The addition of chelating compounds in the soil could result in an increasing of the Cr oxidizable fraction mainly composed by Cr species associated to the organ mineral complexes. (C) 2020 Elsevier Ltd. All rights reserved.