Synthesis and characterization of a novel 3-amino-1,2,4-triazole lead(II) coordination polymer

被引：2

作者：

Sozerli, Sebnem Esen ^{[1
]}

Ozen, Arzu ^{[1
]}

Kani, Ibrahim ^{[2
]}

Demir, Deniz ^{[1
]}

机构：

[1] Celal Bayar Univ, Fac Arts & Sci, Dept Chem, Muradiye, Manisa, Turkey

[2] Anadolu Univ, Fac Sci, Dept Chem, Eskisehir, Turkey

来源：

TURKISH JOURNAL OF CHEMISTRY | 2014年 / 38卷 / 04期

关键词：

3-Amino-1,2,4-triazole; 1,2,4-triazole; acetate; lead(II) complexes; coordination polymer; ORGANIC FRAMEWORK MATERIALS; CRYSTAL-STRUCTURE; PB(II) COORDINATION; EMISSION PROPERTIES; LIGANDS; COMPLEX; 2,2'-BIPYRIDINE; CARBOXYLATE; DICARBOXYLATE; CONSTRUCTION;

D O I：

10.3906/kim-1308-19

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel [Pb-2(mu-atrz)(2)(mu-CH3COO)(CH3COO)](n) (atrz = 3 amino-1,2,4-triazole) complex was synthesized and characterized by IR spectroscopy, thermogravimetric analysis, and single crystal X-ray diffraction. The molecular structure shows that the complex is a coordination polymer in which there are 2 different lead(II) ions with coordination number of 5, Pb(2), and, with a coordination number of 4, Pb(1). Each atrz acts as a bridging ligand between 2 Pb(II) ions through the 2 adjacent nitrogen atoms of the triazole ring. The acetate anions show different types of coordination mode: one acts as a bridge by coordination of the same oxygen atom with Pb(II) ions and the other as a monodentate coordination by one of the oxygen atoms with Pb(2).

引用

页码：671 / 678

页数：8

共 43 条

[31] A first 1,2,4-triazole PbII complex:: Thermal, spectroscopic and structural studies, [Pb2(trz)2(CH3COO)(NO2)]n
Soudi, Ali Akbar
Morsali, Ali
Moazzenchi, Sahar
[J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2006, 9 (12) : 1259 - 1262
[32] Spek A.L., 2008, PLATON MULTIPURPOSE
[33] Self-assembly of a 1D helical coordination polymeric lead(II) complex with Pb•••O(perchlorate)•••Pb scaffoldings
Wang, XB
Vittal, JJ
[J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2003, 6 (08) : 1074 - 1077
[34] Synthesis and Crystal Structure of a New Pb(II) Coordination Polymer Constructed by a 1,10-Phenanthroline Derivative and a Flexible Dicarboxylate
Wang, Xiu-Yan
Guo, Jia
Wang, Hui-Lian
Wang, Qing-Wei
[J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2011, 66 (06): : 647 - 650
[35] Synthesis and Crystal Structure of a Lead(II) Complex with N-[(3-Carboxyphenyl)-sulfonyl]glycine and 4,4' -Bipyridine
Wen, Gui-Lin
Yuan, Shuai
[J]. SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2010, 40 (03) : 207 - 210
[36] A novel three-dimensional coordination polymer involving Pb-Pb interactions and three different hemidirected lead(II) coordination spheres:: X-ray crystal structure of tris(1,10-phenanthroline-κN1,κN10)-bis[{μ3-[5-(sulfo-κO)benzene-1,3-dicarboxylate(3-)-κO1,κO1′:: κO2,κO2′:κO2]}trilead (Pb-Pb) trihydrate ([Pb3(phen)3(H2O)2(sip)2]n • 3 H2O)
Xiao, HP
Morsali, A
[J]. HELVETICA CHIMICA ACTA, 2005, 88 (09) : 2543 - 2549
[37] Mono- and bilayered lead(II)-bpno polymers with unusual low energy emission properties (bpno=4,4′-bipyridine N,N′-dioxide)
Xu, YQ
Yuan, DQ
Han, L
Ma, E
Wu, MY
Lin, ZZ
Hong, MC
[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2005, (11) : 2054 - 2059
[38] Syntheses, crystal structures, and photophysical properties of two 2-D coordination polymers
Yan, Li
Li, Chuan-Bi
[J]. JOURNAL OF COORDINATION CHEMISTRY, 2012, 65 (24) : 4288 - 4298
[39] Structural variation from 1D to 3D: Effects of ligands and solvents on the construction of lead(II)-organic coordination polymers
Yang, Jin
Li, Guo-Dong
Cao, Jun-Jun
Yue, Qi
Li, Guang-Hua
Chen, Jie-Sheng
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (11) : 3248 - 3261
[40] A three-dimensional lead(II) polymer with bridging saccharinate and unusually coordinated acetate ligands -: Synthesis, IR spectra, and crystal structure of [Pb(H2O)(μ-OAc)(μ-sac)]n
Yilmaz, VT
Hamamci, S
Andac, O
Guven, K
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2003, 629 (01): : 172 - 176

← 1 2 3 4 5 →