Ferrous metal-organic frameworks with stronger coordinatively unsaturated metal sites for persulfate activation to effectively degrade dibutyl phthalate in wastewater

被引:109
作者
Chi, Haiyuan [1 ,2 ]
Wan, Jinquan [1 ,2 ]
Ma, Yongwen [1 ,2 ]
Wang, Yan [1 ,2 ]
Ding, Su [1 ]
Li, Xitong [1 ]
机构
[1] South China Univ Technol, Coll Environm & Energy, Guangzhou 510006, Guangdong, Peoples R China
[2] Guangdong Plant Fiber High Valued Cleaning Utiliz, Guangzhou 510006, Guangdong, Peoples R China
基金
中国国家自然科学基金;
关键词
Advanced oxidation technology; Persulfate; Dibutyl phthalate; Metal organic framework; Heterogeneous catalyst; GLASSY-CARBON ELECTRODE; ZERO-VALENT IRON; ORANGE G; OXIDATION; PERFORMANCE; ACID; MIL-100(FE); ADSORPTION; MECHANISM; CATALYST;
D O I
10.1016/j.jhazmat.2019.05.081
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
In the advanced oxidation system (AOPs) of persulfate (PS) activated by iron-based metal-organic frameworks (MOFs), aim at solving the problem on the treatment difficulty of wastewater with low concentration persistent organic pollutants (POPs), a new type of ferrous metal-organic frameworks (Fe(II)-MOFs) with stronger coordinatively unsaturated metal sites (CUS) was successfully synthesized by different methods. The catalytic performance of Fe(II)-MOFs was were obtained by the experiment of degrading dibutyl phthalate (DBP) through persulfate activation. It was found that the degradation efficiency of 0.018 mmol L-1 DBP was 86.73% under the conditions of 0.40 g L-1 and 2.70 mmol L-1 persulfate at a wide pH range. At the same time, the crystal structure and surface morphology of Fe(II)-MOFs did not change significantly after reaction and it could still maintain the removal rate of 75.44% of the target pollutants in the fifth cycle. Furthermore, in the consideration of iron valence state of MOFs before and after reaction, and combined with the analysis of electrochemical properties, the possible mechanism of PS activation was proposed, namely the metastable electron layer inside ferrous ions produced the internal power to accelerate the electron transfer in CUS, leading to improve the activity of the catalyst.
引用
收藏
页码:163 / 171
页数:9
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