Silica-Supported Molecular Catalysts for Tandem Reactions

被引：44
|
作者：
Jin, Ronghua [1 ]
Zheng, Dongsong [1 ]
Liu, Rui [1 ]
Liu, Guohua [1 ]
机构：
[1] Shanghai Normal Univ, Key Lab Resource Chem, Minist Educ, Shanghai Key Lab Rare Earth Funct Mat, 100 Guilin Rd, Shanghai, Peoples R China
来源：
CHEMCATCHEM | 2018年 / 10卷 / 08期
关键词：
asymmetric synthesis; heterogeneous catalysis; mesoporous material; supported catalysis; tandem reaction; ONE-POT SYNTHESIS; ASYMMETRIC TRANSFER HYDROGENATION; ORDERED MESOPOROUS MATERIALS; INORGANIC HYBRID MATERIALS; ORGANIC FUNCTIONAL-GROUPS; BOND-FORMING REACTIONS; GRAFTED CHIRAL BASES; HETEROGENEOUS CATALYSIS; COUPLING REACTIONS; CASCADE REACTIONS;
D O I：
10.1002/cctc.201701718
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The development of silica-supported molecular catalysts for tandem reactions is an important research direction of heterogeneous catalysis. Besides their significant merits in sustainable catalytic processes, numerous strategies have been utilized to construct silica-supported molecular catalysts. Here, we emphasize tandem reactions and summarize the recent advances in sequential organic transformations. This paper is composed of four parts. The beginning part introduces silica as supports. The second part provides a large number of examples for the construction of non-chiral molecular catalysts used for tandem reactions. The third part offers an outline for the construction of chiral molecular catalysts used for enantioselective tandem reactions. Finally, the perspectives for the further development of silica-supported molecular catalysts for tandem reactions are addressed.
引用
收藏
页码：1739 / 1752
页数：14
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