Vapor-Liquid Equilibrium for the trans-2-butene plus methanol, plus ethanol, plus 2-propanol, plus 2-butanol, and plus 2-methyl-2-propanol systems at 332 K

被引:10
作者
Zaytseva, A [1 ]
Uusi-Kyyny, P [1 ]
Pokki, JP [1 ]
Pakkanen, M [1 ]
Aittamaa, J [1 ]
机构
[1] Aalto Univ, Dept Chem Technol, FIN-02015 Helsinki, Finland
关键词
D O I
10.1021/je0341256
中图分类号
O414.1 [热力学];
学科分类号
摘要
An automated static total pressure measurement apparatus was used to measure isothermal vapor-liquid equilibria for five binary systems: trans-2-butene + methanol, + ethanol, + 2-propanol, + 2-butanol, and + 2-methyl-2-propanol at 332.3 K. Error analysis of the measured results has been presented. All systems exhibited positive deviation from Raoult's law. The trans-2-butene + methanol and trans-2-butene + ethanol systems showed azeotropic behavior.
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收藏
页码:1168 / 1174
页数:7
相关论文
共 18 条
[1]   STATISTICAL THERMODYNAMICS OF LIQUID-MIXTURES - NEW EXPRESSION FOR EXCESS GIBBS ENERGY OF PARTLY OR COMPLETELY MISCIBLE SYSTEMS [J].
ABRAMS, DS ;
PRAUSNITZ, JM .
AICHE JOURNAL, 1975, 21 (01) :116-128
[2]  
AITTAMAA J, 2001, USER MANUAL PROGRAM
[3]   DETERMINATION OF ACTIVITY COEFFICIENTS FROM TOTAL PRESSURE MEASUREMENTS [J].
BARKER, JA .
AUSTRALIAN JOURNAL OF CHEMISTRY, 1953, 6 (03) :207-210
[4]  
Daubert T E., 1989, PHYS THERMODYNAMIC P, DOI DOI 10.5860/CHOICE.27-3319
[5]   P-X AND GAMMA-INFINITY DATA FOR THE DIFFERENT BINARY BUTANOL-WATER SYSTEMS AT 50-DEGREES-C [J].
FISCHER, K ;
GMEHLING, J .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1994, 39 (02) :309-315
[6]  
GMEHLING J, 1977, DECHEMA CHEM DATA 1, V1
[7]   Vapour-liquid equilibrium for the 1-butene plus methanol, plus ethanol, plus 2-propanol, plus 2-butanol and plus 2-methyl-2-propanol systems at 326 K [J].
Laakkonen, M ;
Pokki, JP ;
Uusi-Kyyny, P ;
Aittamaa, J .
FLUID PHASE EQUILIBRIA, 2003, 206 (1-2) :237-252
[8]   Henry's constants and infinite dilution activity coefficients of propane, propene, butane, isobutane, 1-butene, isobutene, trans-2-butene, and 1,3-butadiene in 2-propanol at 250-330 K [J].
Miyano, Y .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2004, 49 (02) :368-371
[9]  
Perry R., 1997, PERRYS CHEM ENG HDB, V7th
[10]   Vapour-liquid equilibrium for the cis-2-butene plus methanol, plus ethanol, plus 2-propanol, plus 2-butanol and plus 2-methyl-2-propanol systems at 337 K [J].
Pokki, JP ;
Laakkonen, M ;
Uusi-Kyyny, P ;
Aittamaa, J .
FLUID PHASE EQUILIBRIA, 2003, 212 (1-2) :129-141