Synthesis, structure and magnetism of a novel carboxylate bridged manganese(II) sheet structure containing the first unsupported aqua bridge

被引：11
作者：
Goodwin, JC
Price, DJ
Heath, SL
机构：
[1] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England
[2] Univ Glasgow, Dept Chem, Glasgow G12 8QQ, Lanark, Scotland
来源：
DALTON TRANSACTIONS | 2004年 / 18期
关键词：
D O I：
10.1039/b407495e
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The structural characterisation of a 2D sheet complex {[Mn-2(Hetheidi)(2)(mu-H2O)(H2O)].3H(2)O}(n) 1 [Hetheidi=DL-N-(1-hydroxymethylpropyl) iminodiacetic acid] assembled from the tetradentate ligand Hetheidi and MnCl2 reveals the presence of rare unsupported mu-aqua bridges and novel hydrogen-bonded water channels, which bind the sheets together.
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收藏
页码：2833 / 2835
页数：3
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