Glaser Coupling of Polymers: Side-Reaction in Huisgens "Click" Coupling Reaction and Opportunity for Polymers with Focal Diacetylene Units in Combination with ATRP

被引：40

作者：

Duxbury, Christopher J. ^{[2
]}

Cummins, David ^{[1
]}

Heise, Andreas ^{[1
,3
]}

机构：

[1] Tech Univ Eindhoven, NL-5600 MB Eindhoven, Netherlands

[2] DSM Res & Patents, NL-6160 MD Geleen, Netherlands

[3] Dublin City Univ, Sch Chem Sci, Dublin 9, Ireland

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2009年 / 47卷 / 15期

基金：

爱尔兰科学基金会;

关键词：

atom transfer radical polymerization (ATRP); block copolymers; click chemistry; Glaser coupling; living polymerization; RADICAL POLYMERIZATION; CHEMISTRY; AZIDE; POLYSTYRENE; SURFACES; FUNCTIONALIZATION; CYCLOADDITIONS; CARBOHYDRATE; COPOLYMERS; MONOLAYERS;

D O I：

10.1002/pola.23437

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Atom transfer radical polymerization (ATRP) was used in combination with Glaser type coupling, allowing the clean and efficient formation of symmetrically coupled polymers with a central diacetylene unit. The feasibility of the clean acetylene coupling was investigated with alkyne terminated poly(ethylene glycol) and poly(styrene) obtained by ATRP. The latter allowed subsequent ATRP to be carried out from the coupled products, offering opportunities for the formation of well defined functional materials with central diacetylene units. Glaser coupling was also observed as a side reaction in Huisgens-type "click" reactions of polymeric alkynes with hindered surface azide groups. (C) 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 3795-3802, 2009

引用

页码：3795 / 3802

页数：8

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