Mechanical energy storage performance of an aluminum fumarate metal-organic framework

被引:101
作者
Yot, Pascal G. [1 ]
Vanduyfhuys, Louis [2 ]
Alvarez, Elsa [3 ,4 ]
Rodriguez, Julien [5 ]
Itie, Jean-Paul [6 ]
Fabry, Paul [3 ]
Guillou, Nathalie [3 ]
Devic, Thomas [3 ]
Beurroies, Isabelle [6 ]
Llewellyn, Philip L. [6 ]
Van Speybroeck, Veronique [2 ]
Serre, Christian [3 ]
Maurin, Guillaume [1 ]
机构
[1] Univ Montpellier, Inst Charles Gerhardt Montpellier UMR CNRS UM ENS, F-34095 Montpellier 05, France
[2] Univ Ghent, Ctr Mol Modeling, B-9052 Zwijnaarde, Belgium
[3] Univ Versailles St Quentin, Inst Lavoisier Versailles, UM 8180, F-78035 Versailles, France
[4] DSTF SEPC STEP, PSA Peugeot Citroen Direct Sci & Technol Futures, F-78943 Velizy Villacoublay, France
[5] Aix Marseille Univ, CNRS, MADIREL UMR 7246, Ctr Sci St Jerome, F-13397 Marseille 20, France
[6] Synchrotron Soleil, Lorme Merisiers, F-91192 Gif Sur Yvette, France
基金
欧洲研究理事会;
关键词
PRESSURE WATER INTRUSION; EXPLORATION; ZEOLITE; GUEST; MOF;
D O I
10.1039/c5sc02794b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The aluminum fumarate MOF A520 or MIL-53-FA is revealed to be a promising material for mechanical energy-related applications with performances in terms of work and heat energies which surpass those of any porous solids reported so far. Complementary experimental and computational tools are deployed to finely characterize and understand the pressure-induced structural transition at the origin of these unprecedented levels of performance.
引用
收藏
页码:446 / 450
页数:5
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