Transient analysis of oxygen storage capacity of Pt/CeO2-ZrO2 materials with millisecond- and second-time resolution

被引：18
作者：
Kondratenko, Evgenii V. [1 ]
Sakamoto, Yoshiyuki [2 ]
Okumura, Kohei [2 ]
Shinjoh, Hirofumi [2 ]
机构：
[1] Univ Rostock, Leibniz Inst Catalysis, Branch Berlin, D-12489 Berlin, Germany
[2] Toyota Cent Res & Dev Labs Inc, Nagakute, Aichi 4801192, Japan
来源：
APPLIED CATALYSIS B-ENVIRONMENTAL | 2009年 / 89卷 / 3-4期
关键词：
Oxygen storage capacity; Mechanism; TAP; Platinum; Ceria; CEO2-ZRO2 MIXED OXIDES; SURFACE-AREA; REDOX BEHAVIOR; PARTIAL OXIDATION; 3-WAY CATALYSTS; SYNTHESIS GAS; CO OXIDATION; METHANE; TEMPERATURE; MECHANISM;
D O I：
10.1016/j.apcatb.2009.01.006
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A simple method for determining the speed of oxygen release from Pt/CeO2-ZrO2 materials is proposed. We determined the speed of oxygen release from three differently prepared Pt(1 wt%)/CeO-ZrO2 catalysts by two methods: the method employing temporal analysis of products (TAP) reactor with CO, O-2, and CO2 pulsed gases, and a conventional method with CO and O-2 switch gases. Strong CO2 adsorption precluded correct analysis of oxygen release speed, when it was determined from the amount Of CO2 formed. Therefore, instead Of the amount of CO2. formed, we suggested the t(max) value, defined as the position of maximal intensity Of CO2 transient responses obtained Upon low-intensity (10(15)-10(16) molecules) CO pulsing ill the TAP reactor. Shorter the t(max) Value, higher the rate of oxygen release, because the temperature dependence of the t(max) determined in the present Study resembles the previous results of oxygen release analysis [T. Tanabe, A. Suda, C. Descorme, D. Duprez. H. Shinjoh, M. Sugiura, Stud. Surf. Sci. Catal. 138 (2001) 135]. (C) 2009 Elsevier B.V. All rights reserved.
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收藏
页码：476 / 483
页数：8
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