Copper(I) scorpionate complexes and their application in palladium-mediated [11C]carbonylation reactions

被引：60

作者：

Kealey, Steven ^{[1
]}

Miller, Philip W. ^{[1
]}

Long, Nicholas J. ^{[1
]}

Plisson, Christophe ^{[2
]}

Martarello, Laurent ^{[2
]}

Gee, Antony D. ^{[1
,2
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England

[2] Univ London Imperial Coll Sci Technol & Med, GlaxoSmithKline, Clin Imaging Ctr, Hammersmith Hosp, London W12 0NN, England

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 25期

关键词：

OXIDATIVE CARBONYLATION; EFFICIENT SYNTHESIS; ALIPHATIC-AMINES; UREAS; CHEMISTRY; CATALYST; MONOXIDE; REACTOR; O2;

D O I：

10.1039/b906166e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Solutions of copper(I) tris( pyrazolyl) borate complexes have been used to greatly improve the solubility of [C-11] carbon monoxide, enabling it to be used in low-pressure, 'one-pot' palladium-mediated carbonylation reactions to form C-11-radiolabelled amides and ureas for use in positron emission tomography.

引用

页码：3696 / 3698

页数：3

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