Mechanism and kinetics of nitroxide-controlled free radical polymerization. Thermal decomposition of 2,2,6,6-tetramethyl-1-polystyroxypiperidines

被引：115

作者：

Ohno, K ^{[1
]}

Tsujii, Y ^{[1
]}

Fukuda, T ^{[1
]}

机构：

[1] KYOTO UNIV,INST CHEM RES,UJI,KYOTO 611,JAPAN

来源：

MACROMOLECULES | 1997年 / 30卷 / 08期

关键词：

D O I：

10.1021/ma961502t

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The decomposition rate constants of two model compounds BS-TEMPO and PS-TEMPO were determined. It was observed that in the TEMPO-mediated polymerization of styrene, the decomposition of the active chain ends would occur less seriously than implied by the experiments with S-TEMPO but still at an important level especially at high temperature.

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页码：2503 / 2506

页数：4

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