2,2′-Biphenol-1,4-diazabicyclo[2.2.2]octane (2/1), a three-dimensional framework built from O-H•••O, O•••N, N-H•••O and C-H•••π(arene) hydrogen bonds

被引：7
|
作者：
Glidewell, C [1 ]
Ferguson, G
Gregson, RM
Lough, AJ
机构：
[1] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland
[2] Univ Toronto, Lash Miller Chem Labs, Toronto, ON M5S 3H6, Canada
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1999年 / 55卷
关键词：
D O I：
10.1107/S0108270199011440
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In the 2:1 adduct of 2,2'-biphenol and 1,4-diazabicyclo[2.2.2]octane, 2C(12)H(10)O(2). C6H12N2, there are eight molecules of the biphenol and four molecules of the amine in the asymmetric unit, and several of these components exhibit orientational disorder even at 100 K. Each biphenol unit contains an intramolecular O-H ... O hydrogen bond [O ... O range for the ordered components 2.594(6) to 2.668(5) Angstrom]. Each of the amines is hydrogen bonded to two biphenol units [O ... N range for the ordered components 2.521(7) to 2.594(6) Angstrom], so forming four independent three-molecule aggregates. These aggregates are further linked by an extensive series of C-H ...pi(arene) interactions into a continuous three-dimensional framework.
引用
收藏
页码：2136 / 2140
页数：5
相关论文
共 50 条
  • [41] 4-iodoanilinium 3-nitrophthalate(1-):: tripartite sheets built from O-H•••O and N-H•••O hydrogen bonds
    Glidewell, C
    Low, JN
    Skakle, JMS
    Wardell, JL
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2003, 59 (09): : O509 - O511
  • [42] 2-Amino-5-iodobenzohydroxamic acid:: supramolecular aggregation through two-dimensional networks of N-H•••O, O-H•••N and C-H•••O interactions
    Vembu, Nagarajan
    Linden, Anthony
    Lee, Jean
    Kelly, John G.
    Nolan, Kevin B.
    Devocelle, Marc
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : O5083 - O5085
  • [43] Anharmonicity in the vibrational modes associated with H-H, N-H, O-H, and C-H bonds
    Limpijumnong, S
    HYDROGEN IN SEMICONDUCTORS, 2004, 813 : 119 - 130
  • [44] Ethyl N-(2-benzylamino-6-benzyloxy-5-nitrosopyrimidin-4-yl)glycinate:: sheets built from a three-centre N-H•••(N,O), and two-centre C-H •••O and C-H•••π(arene) hydrogen bonds
    Low, JN
    Glidewell, C
    Quesada, A
    Nogueras, M
    Sánchez, A
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2002, 58 : o425 - O427
  • [45] APA2[Zn3(HPO4)4(H2O)2], a Layered Zincophosphate Featuring Template-to-Framework N-H•••O and "Synergic" Framework-to-Template O-H•••N Hydrogen Bonds and C-H•••O Interactions (APA=2-Amino-1-phenyleneammonium, C6H9N2+)
    Aughey, Joel C.
    Harrison, William T. A.
    Slawin, Alexandra M. Z.
    CRYSTALS, 2012, 2 (03) : 1146 - 1154
  • [46] O-Phenyl (triphenylphosphoniomethyl) phosphonate phenol solvate:: supramolecular structure generated by O-H •••O, C-H•••O and C-H•••π(arene) hydrogen bonds
    Checinska, Lilianna
    Rybarczyk-Pirek, Agnieszka J.
    Kudzin, Zbigniew H.
    Okruszek, Andrzej
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2007, 63 (09): : O504 - O506
  • [47] 4-bromo-β-(2-oxoquinolin-4-yloxy)cinnamonitrile:: a three-dimensional framework structure built from N-H•••O and C-H•••O hydrogen bonds, and bromo-carbonyl and aromatic π-π stacking interactions
    Cruz, Silvia
    de la Torre, Jose M.
    Cobo, Justo
    Low, John N.
    Glidewell, Christopher
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2006, 62 : O3056 - O3058
  • [48] 1-(4-Methylphenylsulfonyl)-1H-1,2,3-benzotriazole:: sheets built from C-H•••N, C-H•••O and C-H•••π(arene) hydrogen bonds
    Rodríguez, R
    Nogueras, M
    Cobo, J
    Low, JN
    Glidewell, C
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : O2795 - O2797
  • [49] Nitroaniline derivatives of 2-oxo-1-naphthylideneamines -: Molecular self-assembling via C-H•••O intermolecular hydrogen bonds and stabilization of O-H•••N and N-H•••O tautomers in solution and solid state
    Popovic, Z
    Pavlovic, G
    Roje, V
    Doslic, N
    Matkovic-Calogovic, D
    Leban, I
    STRUCTURAL CHEMISTRY, 2004, 15 (06) : 587 - 598
  • [50] Strength of the N-H•••O=C and C-H•••O=C bonds in formamide and N-methylacetamide dimers
    Vargas, R
    Garza, J
    Friesner, RA
    Stern, H
    Hay, BP
    Dixon, DA
    JOURNAL OF PHYSICAL CHEMISTRY A, 2001, 105 (20): : 4963 - 4968
12345