2,2′-Biphenol-1,4-diazabicyclo[2.2.2]octane (2/1), a three-dimensional framework built from O-H•••O, O•••N, N-H•••O and C-H•••π(arene) hydrogen bonds

被引：7
|
作者：
Glidewell, C [1 ]
Ferguson, G
Gregson, RM
Lough, AJ
机构：
[1] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland
[2] Univ Toronto, Lash Miller Chem Labs, Toronto, ON M5S 3H6, Canada
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1999年 / 55卷
关键词：
D O I：
10.1107/S0108270199011440
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In the 2:1 adduct of 2,2'-biphenol and 1,4-diazabicyclo[2.2.2]octane, 2C(12)H(10)O(2). C6H12N2, there are eight molecules of the biphenol and four molecules of the amine in the asymmetric unit, and several of these components exhibit orientational disorder even at 100 K. Each biphenol unit contains an intramolecular O-H ... O hydrogen bond [O ... O range for the ordered components 2.594(6) to 2.668(5) Angstrom]. Each of the amines is hydrogen bonded to two biphenol units [O ... N range for the ordered components 2.521(7) to 2.594(6) Angstrom], so forming four independent three-molecule aggregates. These aggregates are further linked by an extensive series of C-H ...pi(arene) interactions into a continuous three-dimensional framework.
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收藏
页码：2136 / 2140
页数：5
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