Investigation of the Reasons for Capacity Fading in Li-Ion Battery Cells

被引:55
作者
Ziv, Baruch [1 ]
Borgel, Valentina [1 ]
Aurbach, Doron [1 ]
Kim, Jung-Hyun [2 ]
Xiao, Xingcheng [2 ]
Powell, Bob R. [2 ]
机构
[1] Bar Ilan Univ, Dept Chem, IL-52900 Ramat Gan, Israel
[2] Gen Motors Global Res & Dev Ctr, Chem & Mat Syst Lab, Warren, MI 48090 USA
基金
美国国家科学基金会;
关键词
ELECTROCHEMICAL-BEHAVIOR; ELEVATED-TEMPERATURES; CYCLING PERFORMANCE; LITHIUM BATTERIES; SPINEL OXIDES; ELECTRODES; MECHANISMS; MN; STORAGE; FADE;
D O I
10.1149/2.0731410jes
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Investigation of the failure mechanisms of Li-ion batteries and the consequences of their failure is of vital importance to the design of durable batteries. In this work, we examined the electrochemical performance of half and full Li-ion battery cells with several cathode materials including LiMn0.8Fe0 2PO4 (LMFP), LiNi0.5Mn1.5O4 (LMNO), and Li[LixNiyCozMn1-x-y-z]O-2 Li-rich layered oxides (HC-MNC). In contrast to half cells which demonstrated good cycling performance with more than 90% of their initial capacities retained after 100 cycles, the full cells exhibited severe capacity loss. Based on postmortem analyzes of electrodes from cells cycled at 30 and 60 degrees C, using electrochemical, spectroscopic, and microscopic techniques, we conclude that the loss of active lithium ions due to parasitic side reactions is a main reason for capacity fading of Li-ion battery full cells. Structural degradation of the electrodes during cycling is at best a second order effect. (C) 2014 The Electrochemical Society. All rights reserved.
引用
收藏
页码:A1672 / A1680
页数:9
相关论文
共 50 条
  • [21] Determination of the tortuosity of a Li-ion battery separator
    Sun, Wei
    Li, Q. M.
    Xiao, Ping
    Carbone, Paola
    JOURNAL OF ENERGY STORAGE, 2024, 97
  • [22] Hybrid MnO/Ni Li-ion Battery Anode Material with Enhanced Capacity Retention
    Kunduraci, Muharrem
    INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2018, 13 (08): : 7397 - 7407
  • [23] Carbon monolith scaffolding for high volumetric capacity silicon Li-ion battery anodes
    Barrett, Lawrence K.
    Fan, Juichin
    Laughlin, Kevin
    Baird, Sterling
    Harb, John N.
    Vanfleet, Richard R.
    Davis, Robert C.
    JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 2017, 35 (04):
  • [24] Understanding the capacity fading mechanism in LiNi0.5Mn1.5O4/graphite Li-ion batteries
    Kim, Jung-Hyun
    Pieczonka, Nicholas P. W.
    Li, Zicheng
    Wu, Yan
    Harris, Stephen
    Powell, Bob R.
    ELECTROCHIMICA ACTA, 2013, 90 : 556 - 562
  • [25] High-capacity graphene oxide/graphite/carbon nanotube composites for use in Li-ion battery anodes
    Zhang, Jingxian
    Xie, Zhengwei
    Li, Wen
    Dong, Shaoqiang
    Qu, Meizhen
    CARBON, 2014, 74 : 153 - 162
  • [26] Revisit of metallothermic reduction for macroporous Si: compromise between capacity and volume expansion for practical Li-ion battery
    Choi, Sinho
    Bok, Taesoo
    Ryu, Jaegeon
    Lee, Jung-In
    Cho, Jaephil
    Park, Soojin
    NANO ENERGY, 2015, 12 : 161 - 168
  • [27] Physically-based reduced-order capacity loss model for graphite anodes in Li-ion battery cells
    Jin, Xing
    Vora, Ashish
    Hoshing, Vaidehi
    Saha, Tridib
    Shaver, Gregory
    Garcia, R. Edwin
    Wasynczuk, Oleg
    Varigonda, Subbarao
    JOURNAL OF POWER SOURCES, 2017, 342 : 750 - 761
  • [28] Sodium-Ion Battery: Can It Compete with Li-Ion?
    Kim, Haegyeom
    ACS MATERIALS AU, 2023, 3 (06): : 571 - 575
  • [29] A feedback charge strategy for Li-ion battery cells based on Reference Governor
    Romagnoli, Raffaele
    Couto, Luis D.
    Goldar, Alejandro
    Kinnaert, Michel
    Garone, Emanuele
    JOURNAL OF PROCESS CONTROL, 2019, 83 : 164 - 176
  • [30] An ab initio investigation of LiCoBO3 as Li-ion battery cathode material
    Mennaoui, O.
    Masrour, R.
    Hlil, E. K.
    COMPUTATIONAL AND THEORETICAL CHEMISTRY, 2023, 1226