Palladium catalyzed cross-coupling reactions for phosphorus-carbon bond formation

被引：285

作者：

Schwan, AL ^{[1
]}

机构：

[1] Univ Guelph, Dept Chem & Biochem, Guelph, ON N1G 2W1, Canada

来源：

CHEMICAL SOCIETY REVIEWS | 2004年 / 33卷 / 04期

关键词：

D O I：

10.1039/b307538a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Underappreciated in the realm of palladium catalyzed cross-coupling chemistry is the formation of phosphorous-carbon bonds. This tutorial review summarises a collection of important contributions in the area, providing a flavour of the many types of phosphorus species that are participants in palladium catalyzed phosphorus-carbon bond formation. Recent developments include the usage of the cross-coupling reaction for preparation of phosphine ligands and the involvement of low molecular weight phosphinic acid derivatives for the synthesis of unsaturated phosphinic and phosphonic acid derivatives. Mechanistic cycles are offered in some instances. Stereochemical issues are addressed where applicable. The literature is covered to mid 2003.

引用

页码：218 / 224

页数：7

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