Synthesis of amino-functionalized MIL-101(Cr) with large surface area

被引：34

作者：

Li, Xiaolin ^{[1
]}

Mao, Ying ^{[1
]}

Leng, Kunyue ^{[1
]}

Ye, Gan ^{[1
]}

Sun, Yinyong ^{[1
]}

Xu, Wei ^{[2
]}

机构：

[1] Harbin Inst Technol, Sch Chem & Chem Engn, MIIT Key Lab Crit Mat Technol New Energy Convers, Harbin 150001, Peoples R China

[2] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China

来源：

MATERIALS LETTERS | 2017年 / 197卷

关键词：

MIL-101(Cr); MIL-101-NH2; MIL-101(Cr)-NO2; Functionalization; MOFs; METAL-ORGANIC FRAMEWORKS; CATALYSIS; ENCAPSULATION; SORPTION; SITES; MOFS; CO2;

D O I：

10.1016/j.matlet.2017.03.034

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Amino-functionalized metal-organic frameworks have attracted much attention because of their potential applications in many fields such as catalysis, adsorption and separation of CO2, further modification. In this work, we report that amino-functionalized MIL-101(Cr) with a large BET surface area of 3262 m(2)/g has been successfully synthesized by the reduction of MIL-101(Cr)-NO2 prepared under solvent-free conditions. Additionally, it has been demonstrated that the obtained material with high surface area exhibited superior catalytic activity in Henry reaction. (C) 2017 Elsevier B.V. All rights reserved.

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页码：192 / 195

页数：4

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