Asymmetric Michael addition reactions of 2-silyloxyfurans catalyzed by binaphthyldiimine-Ni(II) complexes

被引：76

作者：

Suga, H ^{[1
]}

Kitamura, T ^{[1
]}

Kakehi, A ^{[1
]}

Baba, T ^{[1
]}

机构：

[1] Shinshu Univ, Fac Engn, Dept Chem & Mat Engn, Wakasato, Nagano 3808553, Japan

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 12期

关键词：

D O I：

10.1039/b402826k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

N,N'-Bis(2-quinolylmethylene)-1,1'-binaphthyl-2,2'-diamine-Ni(II) complex and analogous complexes were found to be efficient chiral Lewis acid catalysts for the asymmetric Michael addition reactions between 2-silyloxyfurans and 3-alkenoyl-2-oxazolidinones, for which asymmetric inductions of up to 97% ee were obtained.

引用

页码：1414 / 1415

页数：2

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