Nanostructured CuO/reduced graphene oxide composite for hybrid supercapacitors

被引:151
作者
Purushothaman, Kamatchi Kamaraj [1 ]
Saravanakumar, Balakrishanan [2 ]
Babu, Inbamani Manohara [3 ]
Sethuraman, Balasubramanian [1 ]
Muralidharan, Gopalan [3 ]
机构
[1] SRM Grp, TRP Engn Coll, Dept Phys, Irungalur, Tamil Nadu, India
[2] Mahalingam Coll Engn & Technol, Fac Phys, Pollachi, Tamil Nadu, India
[3] Gandhigram Rural Univ, Dept Phys, Gandhigram 624302, Tamil Nadu, India
关键词
HIGH-PERFORMANCE SUPERCAPACITORS; ULTRAHIGH-ENERGY DENSITY; ELECTROCHEMICAL CAPACITORS; ELECTRODE MATERIALS; CHEMICAL SENSORS; FABRICATION; NANOSHEETS; BATTERY;
D O I
10.1039/c4ra02107j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
To address the issues such as low ionic conductivity, poor electrode kinetics and cyclic stability, the strategy of combining carbon-based materials with transition metal oxide (TMO) is adopted. In this article, the preparation of CuO/reduced graphene oxide (RGO) nano-composite electrodes by a simple, low cost hydrothermal method is described. This hybrid nanocomposite exhibits a high specific capacitance of 326 F g(-1) at a current density of 0.5 A g(-1). It shows a high energy density of 65.7 W h kg(-1) at a power density of 302 W kg(-1). Further, this material does not exhibit any measureable degradation in electrochemical performance, even after 1500 cycles. Symmetric hybrid capacitors exhibit a specific capacitance of 97 F g(-1) at 0.2 A g-1 with a power density of 72 W kg(-1). These superior electrochemical features demonstrate that the CuO/ =RGO hybrid nanocomposite is a promising material for next-generation supercapacitor systems.
引用
收藏
页码:23485 / 23491
页数:7
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