Synthesis and characterization of Cu3P hollow spheres by a facile soft-template process

被引：16

作者：

Wang, Xinjun ^{[1
]}

Wan, Fuquan ^{[1
]}

Liu, Juan ^{[1
]}

Gao, Youjun ^{[1
]}

Jiang, Kai ^{[1
]}

机构：

[1] Henan Normal Univ, Coll Chem & Environm Sci, Xinxiang 453007, Henan, Peoples R China

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2009年 / 474卷 / 1-2期

关键词：

Metals; Nanostructures; Scanning and transmission electron microscopy; COPPER PHOSPHIDE CU3P; MICROSPHERES; CAPSULES; ENCAPSULATION; FABRICATION; PARTICLES; ADDITIONS; ROUTE;

D O I：

10.1016/j.jallcom.2008.06.052

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Hollow Cu3P microspheres have been successfully synthesized by a facile ethylenediamine tetraacetic acid (EDTA) mediated solvothermal route using CuSO4 center dot 5H(2)O and yellow phosphorus as starting materials in a mixture solution of ethylene glycol (EG), ethanol and water. The formation of these hollow spheres is attributed to the oriented aggregation of Cu3P nanocrystals around the gas-liquid interface between PH3 and the mixture solution. The possible growth mechanism is proposed. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：233 / 236

页数：4

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