Electrochemical Polymerization of Thiophene and Poly (3-hexyl) thiophene, Nanocomposites with TiO2, and Corrosion Protection Behaviors

被引：5

作者：

Ates, Murat ^{[1
,2
]}

Dolapdere, Aysegul ^{[1
]}

机构：

[1] Namik Kemal Univ, Fac Arts & Sci, Dept Chem, Tekirdag, Turkey

[2] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90024 USA

来源：

POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING | 2015年 / 54卷 / 17期

关键词：

Al1050; Anticorrosion; Nanocomposite; Polythiophene; Poly(3-hexylthiophene); TiO2; CONDUCTING POLYMERS; FILMS; POLYTHIOPHENE; IMPEDANCE; SURFACE; STEEL;

D O I：

10.1080/03602559.2015.1036450

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Thiophene, 3-hexylthiophene, and their nanocomposites with TiO2 were electropolymerized on Al1050 electrode by chronoamperometric technique. Different concentrations of thiophene and 3-hexylthiophene homopolymers and their nanocomposites with TiO2 (2% in total content) were characterized by attenuated total reflection Fourier transform infrared spectroscopy, scanning electron microscopy, energy dispersion X-ray analysis, and electrochemical impedance spectroscopy. The anticorrosion tests for homopolymers and nanocomposite films were examined on Al1050 in 3.5% NaCl solution. Poly(3-hexylthiophene)/TiO2 nanocomposite films gave the highest protection efficiency of 98% because the amount of defects was much lower than that for the poly(3-hexylthiophene), polythiophene, and polythiophene/TiO2 films.

引用

页码：1780 / 1786

页数：7

共 31 条

[1] A facile and template-free method for preparation of polythiophene microspheres and their dispersion for waterborne corrosion protection coatings [J].

Ai, L. ;

Liu, Y. ;

Zhang, X. Y. ;

Ouyang, X. H. ;

Ge, Z. Y. .

SYNTHETIC METALS, 2014, 191 :41-46

[2] Sonoelectrochemical and Electrochemical Synthesis of Polypyrrole Films on St-12 Steel and Their Corrosion and Morphological Studies [J].

Ashassi-Sorkhabi, H. ;

Bagheri, R. .

ADVANCES IN POLYMER TECHNOLOGY, 2014, 33 (03)

[3]

Ates M, 2009, INT J ELECTROCHEM SC, V4, P980

[4] The corrosion protection of mild steel by single layered polypyrrole and multilayered polypyrrole/poly(5-amino-1-naphthol) coatings [J].

Bereket, Goezen ;

Hur, Evrim .

PROGRESS IN ORGANIC COATINGS, 2009, 65 (01) :116-124

[5] Multichromic conducting copolymer of 1-benzyl-2,5-di(thiophen-2-yl)-1H-pyrrole with EDOT [J].

Camurlu, Pinar ;

Tarkuc, Simge ;

Sahmetlioglu, Ertugrul ;

Akhmedov, Idris Mecidoglu ;

Tanyeli, Cihangir ;

Toppare, Levent .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2008, 92 (02) :154-159

[6] Conducting polymers for corrosion protection: a review [J].

Deshpande, Pravin P. ;

Jadhav, Niteen G. ;

Gelling, Victoria J. ;

Sazou, Dimitra .

JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, 2014, 11 (04) :473-494

[7] The application of some polydentate Schiff base compounds containing aminic nitrogens as corrosion inhibitors for mild steel in acidic media [J].

Emregul, Kaan C. ;

Duzgun, Ece ;

Atakol, Orhan .

CORROSION SCIENCE, 2006, 48 (10) :3243-3260

[8] AN IMPEDANCE STUDY OF POLYANILINE FILMS IN AQUEOUS AND ORGANIC SOLUTIONS [J].

FIORDIPONTI, P ;

PISTOIA, G .

ELECTROCHIMICA ACTA, 1989, 34 (02) :215-221

[9] New application and electrochemical characterization of a nickel-doped mesoporous carbon for supercapacitors [J].

Gnanakan, S. R. P. ;

Karthikeyan, K. ;

Amaresh, S. ;

Cho, S. J. ;

Park, G. J. ;

Lee, Y. S. .

JOURNAL OF ALLOYS AND COMPOUNDS, 2011, 509 (41) :9858-9864

[10] Photovoltaic characterization of hybrid solar cells using surface modified TiO2 nanoparticles and poly(3-hexyl)thiophene [J].

Gunes, Serap ;

Marjanovic, Nenad ;

Nedeljkovic, Jovan M. ;

Sariciftci, Niyazi Serdar .

NANOTECHNOLOGY, 2008, 19 (42)

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