A novel approach to improve the mathematical modelling of the internal reforming process for solid oxide fuel cells using the orthogonal least squares method

被引:22
作者
Sciazko, Anna [1 ,2 ]
Komatsu, Yosuke [2 ]
Brias, Grzegorz [1 ]
Kimijima, Shinji [3 ]
Szmyd, Janusz S. [1 ]
机构
[1] AGH Univ Sci & Technol, Fac Energy & Fuels, Dept Fundamental Res Energy Engn, PL-30059 Krakow, Poland
[2] Shibaura Inst Technol, Grad Sch Engn & Sci, Div Reg Environm Syst, Minuma Ku, Saitama 3378570, Japan
[3] Shibaura Inst Technol, Coll Syst Engn & Sci, Dept Machinery & Control Syst, Minuma Ku, Saitama 3378570, Japan
关键词
Methane/steam reforming; Generalized least squares method; Uncertainty analysis; Reaction kinetics; Solid oxide fuel cells; MASS-TRANSFER PROCESSES; NUMERICAL-ANALYSIS; HEAT-TRANSFER; METHANE; KINETICS; NI/YSZ; ANODE; GAS; SOFC; CH4;
D O I
10.1016/j.ijhydene.2014.07.130
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This paper presents a novel approach to experimental and numerical investigations of the methane/steam reforming reaction process over a nickel/yttria-stabilized zirconia fine powder catalyst. Methane/steam reforming is primarily considered as a hydrogen production process for Solid Oxide Fuel Cells, and therefore its reaction kinetic was investigated experimentally and numerically. The present paper describes the innovative implementation of an orthogonal least squares (generalized least squares: GLS) algorithm for the calculation of the reaction kinetics involving precise information and the uncertainties of the obtained results. The GLS method was applied to evaluate the reaction rate and therefore fractional conversion of methane. An analysis of the mathematical model points out that the experimental inaccuracy could be reduced and allowed for the calculation of the most probable values of kinetic parameters and their uncertainties. The GLS method secures a higher accuracy of measured data and estimates the most probable value of all model parameters. Copyright (C) 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:16372 / 16389
页数:18
相关论文
共 50 条
[41]   Thermodynamic and experimental assessment of proton conducting solid oxide fuel cells with internal methane steam reforming [J].
Lei, Libin ;
Keels, Jayson M. ;
Tao, Zetian ;
Zhang, Jihao ;
Chen, Fanglin .
APPLIED ENERGY, 2018, 224 :280-288
[42]   Electrochemical characteristics and carbon tolerance of solid oxide fuel cells with direct internal dry reforming of methane [J].
Lyu, Zewei ;
Shi, Wangying ;
Han, Minfang .
APPLIED ENERGY, 2018, 228 :556-567
[43]   Internal Partial Oxidation Reforming of Butane and Steam Reforming of Ethanol for Anode-supported Microtubular Solid Oxide Fuel Cells [J].
Sumi, H. ;
Yamaguchi, T. ;
Shimada, H. ;
Fujishiro, Y. ;
Awano, M. .
FUEL CELLS, 2017, 17 (06) :875-881
[44]   Advanced Direct Internal Reforming Concepts for Solid Oxide Fuel Cells Running with Biogas [J].
Tran, D. L. ;
Kubota, A. ;
Sakamoto, M. ;
Tran, Q. T. ;
Sasaki, K. ;
Shiratori, Y. .
SOLID OXIDE FUEL CELLS 15 (SOFC-XV), 2017, 78 (01) :2467-2476
[45]   Dual layered anode support for the internal reforming of methane for solid oxide fuel cells [J].
Lee, Sung Ho ;
Kim, Haekyoung .
CERAMICS INTERNATIONAL, 2014, 40 (04) :5959-5966
[46]   An additional layer in an anode support for internal reforming of methane for solid oxide fuel cells [J].
Park, Young Min ;
Kim, Haekyoung .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2014, 39 (29) :16513-16523
[47]   Applying high efficiency internal reforming catalyst for direct low concentration coal mine methane solid oxide fuel cells [J].
Liu, Chun ;
Li, Xiaoyu ;
Zhang, Jinke ;
Wang, Xinxin ;
Ling, Yihan .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2024, 74 :276-282
[48]   Mathematical modeling of solid oxide fuel cell performance with indirect internal reforming and thermal interaction analysis [J].
Maharluie, Hadis Najafi ;
Rahmani, Mohammad .
ENERGY CONVERSION AND MANAGEMENT, 2024, 316
[49]   Investigation of Internal Reforming Reaction at Low Temperature Using Micro Tubular Solid Oxide Fuel Cell [J].
Watanabe, Naoki ;
Kawakami, Akira ;
Omura, Hajime ;
Hoshiko, Takuya ;
Oe, Toshiharu ;
Ishihara, Tatsumi .
ELECTROCHEMISTRY, 2012, 80 (08) :566-573
[50]   Study on Internal Phenomena of Solid Oxide Fuel Cells Using Liquefied Natural Gas as Fuel [J].
Kim, Min Soo ;
Kim, Young Sang ;
Lee, Young Duk ;
Kim, Minsung ;
Kim, Dong Kyu .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2021, 168 (12)