Synthetic, Structural, and Theoretical Investigation of Guanidinate Complexes Containing Planar Cu6 Cores

被引：10

作者：

Bunge, Scott D. ^{[1
]}

Ocana, Jesus A. ^{[1
]}

Cleland, Travis L. ^{[1
]}

Steele, Jennifer L. ^{[1
]}

机构：

[1] Kent State Univ, Dept Chem, Kent, OH 44242 USA

来源：

INORGANIC CHEMISTRY | 2009年 / 48卷 / 11期

基金：

美国国家科学基金会;

关键词：

RAY CRYSTAL-STRUCTURE; HEXANUCLEAR COPPER(I); NUCLEOPHILIC-SUBSTITUTION; AZOMETHINE DERIVATIVES; LIGANDS; CLUSTER; AROMATICITY; REACTIVITY; THIOLATE; ANALOGS;

D O I：

10.1021/ic9003627

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The addition of diethylcyanamide to a tetra an solution of lithium dialkylamide LiN(CH3)(2) or LiNCH2CH2CH2CH2, Li(PYR), results in the corresponding lithium 1,1,3,3-tetraalkylguanidinate, Li(TAG). The subsequent metathesis reaction of Li(TAG) with CuCl generates hexanuclear copper(I) complexes with the general formula [Cu(mu-TAG)](6), where TAG = DEDMG (1) and DEPYRG (2).

引用

收藏

页码：4619 / 4621

页数：3

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