Deuterium isotope effect in the reaction of anthrone oxidation with molecular oxygen catalyzed with aliphatic amines

被引：1

作者：

Serdyuk, A. A. ^{[1
]}

Kasyanchuk, M. G. ^{[1
]}

Opeida, I. A. ^{[1
]}

机构：

[1] Natl Acad Sci Ukraine, LM Litvinenko Inst Phys Organ & Coal Chem, UA-83114 Donetsk, Ukraine

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2014年 / 84卷 / 02期

关键词：

General Chemistry; Molecular Oxygen; Isotope Effect; Aliphatic Amine; Anthrone;

D O I：

10.1134/S107036321402008X

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Deuterium isotope effect in the process of the amine-catalyzed anthrone oxidation with molecular oxygen was studied. Reaction proceeds by oxygen insertion in C-H bonds in the position 10. Isotope effect is observed only at the stage of the anthranolate anions reaction with oxygen, and not at the stage of their formation. Therefore it is a secondary isotope effect.

引用

页码：209 / 213

页数：5