Nonideal mixing in adsorbed film and micelle of ionic-nonionic surfactant mixtures

被引：48

作者：

Villeneuve, M ^{[1
]}

Sakamoto, H ^{[1
]}

Minamizawa, H ^{[1
]}

Ikeda, N ^{[1
]}

Motomura, K ^{[1
]}

Aratono, M ^{[1
]}

机构：

[1] FUKUOKA WOMENS UNIV,FAC HUMAN ENVIRONM SCI,FUKUOKA 813,JAPAN

来源：

JOURNAL OF COLLOID AND INTERFACE SCIENCE | 1997年 / 194卷 / 02期

关键词：

surface tension; mixed adsorbed film; mixed micelle; thermodynamics; phase diagram; activity coefficient; excess Gibbs energy;

D O I：

10.1006/jcis.1997.5081

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The surface tension of aqueous solutions of dodecylammonium chloride-octyl methyl sulfoxide (OMS) and dodecyltrimethylammonium bromide-OMS mixtures was measured as a function of the total molality of surfactants and the composition of OMS. The results were analyzed according to our thermodynamic procedure; the phase diagrams of adsorption and micelle formation and the diagram illustrating the composition relation between the micelle and the adsorbed film at the critical micelle concentration were drawn. The activity coefficient and excess Gibbs energy in the adsorbed film and the micelle were defined and then evaluated from the phase diagrams. They were found to give useful information on the deviation from ideal mixing and intermolecular interaction in the adsorbed film and micelle. (C) 1997 Academic Press.

引用

页码：301 / 310

页数：10

共 16 条

[1] Miscibility of butanol and cationic surfactant in the adsorbed film and micelle
Villeneuve, M
Ikeda, N
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Aratono, M
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1998, 208 (02) : 388 - 398
[2] Nonideal mixing of dodecyltrimethylammonium halides and nonionic surfactant in adsorbed films and micelles
Matsuda, T
Asoh, Y
Villeneuve, M
Matsubara, H
Takiue, T
Aratono, M
COLLOID AND POLYMER SCIENCE, 2004, 282 (04) : 324 - 329
[3] Nonideal mixing of dodecyltrimethylammonium halides and nonionic surfactant in adsorbed films and micelles
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Yoko Asoh
Masumi Villeneuve
Hiroki Matsubara
Takanori Takiue
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Colloid and Polymer Science, 2004, 282 : 324 - 329
[4] Structure effect on nonideal mixing of alkyl methyl sulfoxide and alkyldimethylphosphine oxide in adsorbed film and micelle
Iyota, H
Todoroki, N
Ikeda, N
Motomura, K
Ohta, A
Aratono, M
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1999, 216 (01) : 41 - 49
[5] Miscibility of binary surfactant mixtures in the adsorbed film and micelle: the effect of size of polar head group
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[6] Micelle formation of Tween 20 nonionic surfactant in imidazolium ionic liquids
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[7] Miscibility of sodium chloride and ionic surfactant in adsorbed film and aggregate
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[8] Miscibility of sodium chloride and ionic surfactant in adsorbed film and aggregate
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[9] Effect of sodium butanoate and sodium hexanoate on micelle formation of model cationic-nonionic and anionic-nonionic surfactant mixtures
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[10] Thermodynamic study on the interaction of imidazolium salts and POE-type nonionic surfactant in the adsorbed film
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Colloid and Polymer Science, 2014, 292 : 1209 - 1215

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