Atomic oxygen resistant behaviors of Mo/diamond-like carbon nanocomposite lubricating films

被引：59

作者：

Ji, Li ^{[1
,2
]}

Li, Hongxuan ^{[1
]}

Zhao, Fei ^{[1
,2
]}

Quan, Weilong ^{[1
,2
]}

Chen, Jianmin ^{[1
]}

Zhou, Huidi ^{[1
]}

机构：

[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China

[2] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China

来源：

APPLIED SURFACE SCIENCE | 2009年 / 255卷 / 07期

基金：

中国国家自然科学基金;

关键词：

Diamond-like carbon; Mo doping; Nanocomposite; Atomic oxygen; Tribological properties; AMORPHOUS-CARBON; RAMAN-SPECTROSCOPY; SPACE; COATINGS; MOS2;

D O I：

10.1016/j.apsusc.2008.11.029

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Mo doped diamond-like carbon (Mo/DLC) films were deposited on Si substrates via unbalanced magnetron sputtering of molybdenum combined with plasma chemical vapor deposition of CH4/Ar. The microstructure of the. films, characterized by transmission electron microscopy and selected area electron diffraction, was considered as a nanocomposite with nano-sized MoC particles uniformly embedded in the amorphous carbon matrix. The structure, morphology, surface composition and tribological properties of the Mo/DLC films before and after the atomic oxygen (AO) irradiation were investigated and a comparison made with the DLC films. The Mo/DLC films exhibited more excellent degradation resistant behaviors in AO environment than the DLC films, and the MoC nanoparticles were proved to play a critical role of preventing the incursion of AO and maintaining the intrinsic structure and excellent tribological properties of DLC films. (C) 2008 Published by Elsevier B. V.

引用

页码：4180 / 4184

页数：5

共 21 条

[1] Preparation of Al2O3/DLC/Au/MoS2 chameleon coatings for space and ambient environments [J].

Baker, C. C. ;

Hu, J. J. ;

Voevodin, A. A. .

SURFACE & COATINGS TECHNOLOGY, 2006, 201 (07) :4224-4229

[2] Nickel-incorporated amorphous carbon film deposited by femtosecond pulsed laser ablation [J].

Benchikh, N ;

Garrelie, F ;

Donnet, C ;

Bouchet-Fabre, B ;

Wolski, K ;

Rogemond, F ;

Loir, AS ;

Subtil, JL .

THIN SOLID FILMS, 2005, 482 (1-2) :287-292

[3] Observation of sp3 bonding in tetrahedral amorphous carbon using visible Raman spectroscopy [J].

Chen, ZY ;

Zhao, JP ;

Yano, T ;

Ooie, T ;

Yoneda, M ;

Sakakibara, J .

JOURNAL OF APPLIED PHYSICS, 2000, 88 (05) :2305-2308

[4]

Donnet C., 2008, TRIBOLOGY DIAMOND LI

[5] Diamond-like carbon films: electron spin resonance (ESR) and Raman spectroscopy [J].

Druz, B ;

Zaritskiy, I ;

Yevtukhov, Y ;

Konchits, A ;

Valakh, M ;

Shanina, B ;

Kolesnik, S ;

Yanchuk, I ;

Gromovoy, Y .

[6]

Erdemir A., 2007, Superlubricity

[7] Interpretation of Raman spectra of disordered and amorphous carbon [J].

Ferrari, AC ;

Robertson, J .

PHYSICAL REVIEW B, 2000, 61 (20) :14095-14107

[8] Degradation of carbon-based materials due to impact of high-energy atomic oxygen [J].

Fujimoto, K ;

Shioya, T ;

Satoh, K .

INTERNATIONAL JOURNAL OF IMPACT ENGINEERING, 2003, 28 (01) :1-11

[9] Stress variations near surfaces in diamond-like amorphous carbon [J].

Fyta, M ;

Kelires, PC .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 2000, 266 :760-764

[10] APPLICATIONS OF SOLID LUBRICANT FILMS IN SPACECRAFT [J].

HILTON, MR ;

FLEISCHAUER, PD .

SURFACE & COATINGS TECHNOLOGY, 1992, 55 (1-3) :435-441

← 1 2 3 →