Recent topics of the metallacycles composed of the heavier group 14 elements

被引：4
作者：
Tanabe, Makoto [1 ]
机构：
[1] Tokyo Inst Technol, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan
来源：
TETRAHEDRON LETTERS | 2014年 / 55卷 / 27期
关键词：
Metallacycles; Dehydrocoupling reactions; Cyclic polymers; Group; 14; elements; SIGMA-CONJUGATED POLYMERS; POLYSILANE HIGH POLYMERS; PI-COMPLEX CHARACTER; BOND FORMATION; PLATINUM COMPLEXES; CRYSTAL-STRUCTURES; PRIMARY SILANES; GE BOND; REACTIVITY; ROUTE;
D O I：
10.1016/j.tetlet.2014.05.012
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
This Letter reviews recent advance of metallacycles with chelating Si-, Ge-, and Sn-ligands. Dehydrogenative bond-forming reactions of organosilanes, -germanes, and -stannanes promoted by Pd and Pt complexes afford four- and five-membered metallacycles composed of heavier group 14 elements. It has a couple of advantages such as easier preparation of the starting compounds and reaction procedure than the common metathesis reactions of dianions with transition metal dihalide complexes. These metallacycles are regarded as possible intermediates in catalytic dehydrocoupling polymerizations or as convenient precursors to form discrete oligomers. (C) 2014 Published by Elsevier Ltd.
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收藏
页码：3641 / 3647
页数：7
相关论文
共 66 条
  • [1] OLIGOMERIZATION OF PHENYLGERMANES BY CATALYTIC DEHYDROCOUPLING
    AITKEN, C
    HARROD, JF
    MALEK, A
    SAMUEL, E
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 349 (03) : 285 - 291
  • [2] POLYMERIZATION OF PRIMARY SILANES TO LINEAR POLYSILANES CATALYZED BY TITANOCENE DERIVATIVES
    AITKEN, C
    HARROD, JF
    SAMUEL, E
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 279 (1-2) : C11 - C13
  • [3] Singly bonded catenated germanes: Eighty years of progress
    Amadoruge, Monika L.
    Weinert, Charles S.
    [J]. CHEMICAL REVIEWS, 2008, 108 (10) : 4253 - 4294
  • [4] Apeloig Y, 2000, EUR J INORG CHEM, P1091
  • [5] Characterization of mononuclear and dinuclear germylplatinum complexes and Ge-Ge bond formation at the platinum center
    Arii, Hidekazu
    Nanjo, Masato
    Mochida, Kunio
    [J]. ORGANOMETALLICS, 2008, 27 (16) : 4147 - 4151
  • [6] Steric Effect of a Phosphane Ligand on the Equilibrium of Ge-Ge Bond Formation at a Platinum Center
    Arii, Hidekazu
    Watanabe, Nakako
    Mochida, Kunio
    Kawashima, Takayuki
    [J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2012, (30) : 4791 - 4794
  • [7] Synthesis of Oligosilanyl Compounds of Group 4 Metallocenes with the Oxidation State +3
    Arp, Henning
    Zirngast, Michaela
    Marschner, Christoph
    Baumgartner, Judith
    Rasmussen, Kenneth
    Zark, Patrick
    Mueller, Thomas
    [J]. ORGANOMETALLICS, 2012, 31 (11) : 4309 - 4319
  • [8] STEREOSELECTIVITY IN THE CATALYTIC OLIGOMERIZATION OF PHENYLSILANE
    BANOVETZ, JP
    STEIN, KM
    WAYMOUTH, RM
    [J]. ORGANOMETALLICS, 1991, 10 (10) : 3430 - 3432
  • [9] Polycondensation of diarylsilanes with aromatic dithiols and the model reaction involving RhCl(PPh(3))(3)-catalyzed Si-S bond formation
    Baruah, JB
    Osakada, K
    Yamamoto, T
    [J]. ORGANOMETALLICS, 1996, 15 (01) : 456 - 459
  • [10] Intermediates in the catalytic dehydrogenative coupling of arylgermanes
    Bender, JE
    Litz, KE
    Giarikos, D
    Wells, NJ
    Holl, MMB
    Kampf, JW
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 1997, 3 (11) : 1793 - 1796
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