Flow-injection analysis for meloxicam based on tris(2,2′-bipyridine) ruthenium(II)-Ce(IV) chemiluminescent system

被引：11

作者：

Ye, Huazhen ^{[1
,2
]}

Qiu, Bin ^{[1
]}

Chen, Jing ^{[1
]}

Lin, Jinming ^{[1
]}

Chen, Guonan ^{[1
]}

机构：

[1] Fuzhou Univ, Dept Chem, Minist Educ, Key Lab Anal & Detect Technol Food Safety, Fuzhou 350002, Fujan, Peoples R China

[2] Fujian Hlth Coll, Fuzhou 350101, Fujan, Peoples R China

来源：

LUMINESCENCE | 2009年 / 24卷 / 04期

关键词：

meloxicam; tris(2,2 '-bipyridine)ruthenium(II); flow-injection; chemiluminescence; PLASMA; OXIDATION;

D O I：

10.1002/bio.1117

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

It was found that meloxicam could enhance the chemiluminescence (CL) of the tris(2,2'-bipyridine) ruthenium(II)Ce(IV) system in the medium of sulfate acid. Based on this phenomenon a new flow-injection system with chemiluminescent detection has been proposed for determination of meloxicam. Under optimum conditions, meloxicam had a good linear relationship with the CL intensity in the concentration range of 6.0 x 10(-4) to 1.0 mu g/mL and the detection limit was 3.7 x 10(-4) mu g/mL. The proposed method was applied to detect meloxicam in tablets and a satisfactory recovery was obtained. The possible mechanism for this CL system is also discussed in this paper. Copyright (C) 2009 John Wiley & Sons, Ltd.

引用

页码：260 / 265

页数：6

共 15 条

[1] Flow-injection chemiluminescent determination of cefprozil using tris (2,2′-bipyridyl) ruthenium (II)-permanganate system [J].