Hybrid coordination polymer constructed from β-octamolybdates linked by quinoxaline and its oxidized product benzimidazole coordinated to binuclear copper(I) fragments

被引：144

作者：

Wu, CD ^{[1
]}

Lu, CZ ^{[1
]}

Zhuang, HH ^{[1
]}

Huang, JS ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

来源：

INORGANIC CHEMISTRY | 2002年 / 41卷 / 22期

关键词：

D O I：

10.1021/ic025668o

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The one-dimensional polymer, [Cu-2(C8H6N2)(2)(C7H6N2)](2)[Mo8O26] (1), which consists of beta-[Mo8O26](4-) anions linked by quinoxaline and its oxidized product benzimidazole ligands coordinated to binuclear copper(1) fragments, provides the first demonstration that the isolated copper(1) complex under hydrothermal conditions "captures" the reduction product of original starting organonitrogen ligand to form a copper(1)-beta-octamolybdate complex.

引用

页码：5636 / 5637

页数：2

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