Interfacially reinforced carbon fiber silicone resin via constructing functional nano-structural silver

被引:58
作者
Li, Ying [1 ]
Zhang, Tong [1 ]
Jiang, Bo [1 ]
Zhao, Liwei [1 ]
Liu, Hu [2 ,3 ]
Zhang, Jiaoxia [2 ,4 ]
Fan, Jincheng [2 ,5 ]
Guo, Zhanhu [2 ]
Huang, Yudong [1 ]
机构
[1] Harbin Inst Technol, Sch Chem & Chem Engn, MIIT Key Lab Crit Mat Technol New Energy Convers, Harbin, Heilongjiang, Peoples R China
[2] Univ Tennessee, Dept Chem & Biomol Engn, ICL, Knoxville, TN 37934 USA
[3] Zhengzhou Univ, Natl Engn Res Ctr Adv Polymer Proc Technol, Minist Educ, Key Lab Mat Proc & Mold, Zhengzhou 450002, Henan, Peoples R China
[4] Jiangsu Univ Sci & Technol, Sch Mat Sci & Engn, Zhenjiang 212003, Jiangsu, Peoples R China
[5] Changsha Univ Sci & Technol, Coll Mat Sci & Engn, Changsha 410114, Hunan, Peoples R China
基金
中国国家自然科学基金;
关键词
Carbon fiber; Composite material; Interfacial property; SURFACE MODIFICATION; EPOXY; NANOPARTICLES; COMPOSITES; TENSILE; FABRICATION; IMPROVEMENT; OXIDATION; STRENGTH; THIOLS;
D O I
10.1016/j.compscitech.2019.107689
中图分类号
TB33 [复合材料];
学科分类号
摘要
The interfacial interaction between carbon fibers (CFs) and resin matrix is an important factor affecting mechanical performances of CF-based composites. In this work, a new approach combining electrodeposition method (EDM) and "Ag-S" bonds was applied to fabricate functional CF-based composites while preserving the mechanical properties of CFs. Silver nanoparticles were first attached on the CF surface by EDM. Then 4-aminothiophenol or 4-mercaptobenzoic acid was linked to Ag surface by Ag-S bonds to incorporate different functional groups onto the fiber surface. The interfacial shear strength was improved pronouncedly while the tensile strength was maintained consistent. The interfacial shear strength of the CFs after functionalized was increased 21.10% and 32.04%, respectively. However, the tensile strength of them decreased no more than 3%. With improved properties, these nanocomposites have potential applications for aerospace, transportation, electronics and other fields.
引用
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页数:6
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