19F NMR: An underused efficient probe for paramagnetic metal centers in bioinorganic solution chemistry

被引：17

作者：

Belle, Catherine ^{[1
]}

Beguin, Claude ^{[1
]}

Hamman, Sylvain ^{[1
]}

Pierre, Jean-Louis ^{[1
]}

机构：

[1] Univ J Fourier, CNRS, Dept Chim Mol, ICMG FR2607,UMR 5250, F-38041 Grenoble 9, France

来源：

COORDINATION CHEMISTRY REVIEWS | 2009年 / 253卷 / 7-8期

关键词：

Metalloproteins; Biomimetic model complexes; F-19; NMR; Paramagnetic metal centers; NUCLEAR-MAGNETIC-RESONANCE; GALACTOSE-OXIDASE; ELECTRON-TRANSFER; FLUORINE NMR; SUBSTRATE-BINDING; CRYSTAL-STRUCTURE; CATECHOL OXIDASE; CHEMICAL-SHIFTS; SPIN RELAXATION; COPPER CENTER;

D O I：

10.1016/j.ccr.2008.06.015

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The application of solution studies in bioinorganic chemistry through paramagnetic F-19 NMR is briefly reviewed. In Section 2 we summarize some theoretical aspects. Selected applications from bioinorganic chemistry (enzymes and models) can be found in Sections 3 and 4. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：963 / 976

页数：14

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