19F NMR: An underused efficient probe for paramagnetic metal centers in bioinorganic solution chemistry

被引：17
|
作者：
Belle, Catherine [1 ]
Beguin, Claude [1 ]
Hamman, Sylvain [1 ]
Pierre, Jean-Louis [1 ]
机构：
[1] Univ J Fourier, CNRS, Dept Chim Mol, ICMG FR2607,UMR 5250, F-38041 Grenoble 9, France
来源：
COORDINATION CHEMISTRY REVIEWS | 2009年 / 253卷 / 7-8期
关键词：
Metalloproteins; Biomimetic model complexes; F-19; NMR; Paramagnetic metal centers; NUCLEAR-MAGNETIC-RESONANCE; GALACTOSE-OXIDASE; ELECTRON-TRANSFER; FLUORINE NMR; SUBSTRATE-BINDING; CRYSTAL-STRUCTURE; CATECHOL OXIDASE; CHEMICAL-SHIFTS; SPIN RELAXATION; COPPER CENTER;
D O I：
10.1016/j.ccr.2008.06.015
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The application of solution studies in bioinorganic chemistry through paramagnetic F-19 NMR is briefly reviewed. In Section 2 we summarize some theoretical aspects. Selected applications from bioinorganic chemistry (enzymes and models) can be found in Sections 3 and 4. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码：963 / 976
页数：14
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