Structure and spectral properties of TCNQ salts with Zn(II) and Ni(II) 2,2′-bipyridine complexes

被引：10

作者：

Vasylets, Grygorii Y. ^{[1
]}

Starodub, Vladimir A. ^{[2
]}

Barszcz, Boleslaw ^{[3
]}

Graja, Andrzej ^{[3
]}

Medviediev, Volodymyr V. ^{[4
]}

Shishkin, Oleg V. ^{[1
,4
]}

Bukrinev, Alexander S. ^{[1
]}

机构：

[1] Kharkov Natl Univ, Fac Chem, UA-61022 Kharkov, Ukraine

[2] Jan Kochanowski Univ, Inst Chem, PL-25406 Kielce, Poland

[3] Polish Acad Sci, Inst Mol Phys, PL-60179 Poznan, Poland

[4] Natl Acad Sci Ukraine, SSI Inst Single Crystals, UA-61001 Kharkov, Ukraine

来源：

SYNTHETIC METALS | 2014年 / 191卷

关键词：

Organic compounds; Chemical synthesis; Crystal structure; Fourier transform infrared spectroscopy; Raman spectroscopy and scattering; REFLECTION SPECTRA; CONDUCTORS; POLYMERS; RAMAN;

D O I：

10.1016/j.synthmet.2014.02.020

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Three new anion-radical TCNQ salts with Zn and Ni 2,2'-bipyridine complexes and appropriate solvent were synthesized as well as structurally and spectrally investigated. Two of the salts show quasi-one dimensional organization of the anions and show distinct anisotropy of the polarized reflection spectra. Both infrared and Raman spectra were extensively investigated using various spectral methods and discussed. The origin of principal absorption IR bands as well as Raman scattering lines was explained according to our quantum chemical calculations. (C) 2014 Published by Elsevier B.V.

引用

页码：89 / 98

页数：10

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