H2SO4/SiO2 as an efficient catalyst for the preparation of phenylhydrazones and 2,4-dinitrophenylhydrazones under solvent-free conditions

被引:16
作者
Kiasat, AR [1 ]
Kazemi, F [1 ]
Nourbakhsh, K [1 ]
机构
[1] Shahid Chamran Univ, Ahvaz, Iran
关键词
2,4-dinitrophenylhydrazone; carbonyl compound; phenylhydrazone; protection; silica gel; solvent free; sulfuric acid;
D O I
10.1080/10426500490422227
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
H2SO4 mixed with silica gel (1:1) by weight produces a white powder which is an effective catalyst for the conversion of carbonyl compounds to their corresponding phenylhydrazones and 2,4-dintrophenylhydrazones under solvent-free conditions.
引用
收藏
页码:569 / 573
页数:5
相关论文
共 8 条
[1]  
CLARK HT, 1986, HDB ORGANIC ANAL, P116
[2]  
Greene T.W., 1991, PROTECTIVE GROUPS OR, V2nd
[3]   Zeolite mediated protection of carbonyl groups [J].
Lalitha, A ;
Pitchumani, K ;
Srinivasan, C .
GREEN CHEMISTRY, 1999, 1 (04) :173-174
[4]  
Metzger JO, 1998, ANGEW CHEM INT EDIT, V37, P2975, DOI 10.1002/(SICI)1521-3773(19981116)37:21<2975::AID-ANIE2975>3.0.CO
[5]  
2-A
[6]   Sulfuric acid on silica-gel: An inexpensive catalyst for aromatic nitration [J].
Riego, JM ;
Sedin, Z ;
Zaldivar, JM ;
Marziano, NC ;
Tortato, C .
TETRAHEDRON LETTERS, 1996, 37 (04) :513-516
[7]   Solvent-free organic synthesis [J].
Tanaka, K ;
Toda, F .
CHEMICAL REVIEWS, 2000, 100 (03) :1025-1074
[8]  
Vogel A.I., 1978, TXB PRACTICAL ORGANI