Electronic Structure of Dendrimer-Au Hybrid Nanoparticle: Hard X-ray Photoemission Study

被引：0

作者：

Murase, Yoshiaki ^{[1
]}

Kitagawa, Takanobu ^{[1
]}

Imamura, Masaki ^{[1
]}

Tanaka, Akinori ^{[1
]}

Yasuda, Hidehiro ^{[1
]}

Negishi, Yuichi

Tsukuda, Tatsuya

Ueda, Shigenori

Yamashita, Yoshiyuki

Yoshikawa, Hideki

Kobayashi, Keisuke

机构：

[1] Kobe Univ, Dept Mech Engn, Nada Ku, Kobe, Hyogo 6578501, Japan

来源：

TRANSACTIONS OF THE MATERIALS RESEARCH SOCIETY OF JAPAN, VOL 33, NO 1 | 2008年 / 33卷 / 01期

关键词：

Hard X-ray photoelectron spectroscopy; Au nanoparticle; Electronic structure;

D O I：

暂无

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

We have carried out the hard X-ray photoemission study of dendrimer-Au hybrid nanoparticles/nanoclusters supported on the highly oriented pyrolytic graphite substrates. From the detailed line-shape analysis for Au 4f core-level photoemission spectrum of dendrimer-Au hybrid nanoparticles with mean diameter of 2.6 nm, it is found that Au 4f core-level spectrum consists of three components. We attribute these components to the interior Au atoms, surface Au atoms, and surface Au atoms bonded to dendrimers. Furthermore, we have investigated the valence-band photoemission spectra. From these results, we discuss the electronic structures and interfacial proper-ties of dendrimer-Au hybrid nanoparticles/nanoclusters.

引用

页码：169 / 172

页数：4

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