Synthesis, X- ray Studies, and Catalytic Efficacy of a Novel Iron Complex Containing an N, O- Type Bidentate Thiazoline Ligand

被引：9
作者：
Amini, Mojtaba [1 ]
Bigdeli, Mina [1 ]
Delsouz-Hafshejani, Sepideh [1 ]
Ellern, Arkady [2 ]
Woo, L. Keith [2 ]
机构：
[1] Univ Maragheh, Fac Sci, Dept Chem, Maragheh, Iran
[2] Iowa State Univ, Dept Chem, Ames, IA 50011 USA
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2014年 / 640卷 / 02期
基金：
美国国家科学基金会;
关键词：
IRON(III) COMPLEX; OXIDATION; SULFIDES; SULFOXIDES; MOIETIES;
D O I：
10.1002/zaac.201300302
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reactions of FeCl3·6H2O and 2-(2′-hydroxyphenyl)-2-thiazoline as a bidentate O-N donor thiazoline ligand (thoz) afford a five-coordinate FeIII complex [Fe(thoz) 2Cl] with a distorted square pyramidal configuration. Complex [Fe(thoz)2Cl] was isolated as air-stable crystalline solids and fully characterized, including by single-crystal X-ray structure analysis. Complex [Fe(thoz)2Cl] shows very efficient reactivity in the oxidation of sulfides to their corresponding sulfoxides using urea hydrogen peroxide (UHP) as the oxidant at room temperature in air. Copyright © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：385 / 389
页数：5
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