Synthesis, X- ray Studies, and Catalytic Efficacy of a Novel Iron Complex Containing an N, O- Type Bidentate Thiazoline Ligand

被引：9

作者：

Amini, Mojtaba ^{[1
]}

Bigdeli, Mina ^{[1
]}

Delsouz-Hafshejani, Sepideh ^{[1
]}

Ellern, Arkady ^{[2
]}

Woo, L. Keith ^{[2
]}

机构：

[1] Univ Maragheh, Fac Sci, Dept Chem, Maragheh, Iran

[2] Iowa State Univ, Dept Chem, Ames, IA 50011 USA

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2014年 / 640卷 / 02期

基金：

美国国家科学基金会;

关键词：

IRON(III) COMPLEX; OXIDATION; SULFIDES; SULFOXIDES; MOIETIES;

D O I：

10.1002/zaac.201300302

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of FeCl3·6H2O and 2-(2′-hydroxyphenyl)-2-thiazoline as a bidentate O-N donor thiazoline ligand (thoz) afford a five-coordinate FeIII complex [Fe(thoz) 2Cl] with a distorted square pyramidal configuration. Complex [Fe(thoz)2Cl] was isolated as air-stable crystalline solids and fully characterized, including by single-crystal X-ray structure analysis. Complex [Fe(thoz)2Cl] shows very efficient reactivity in the oxidation of sulfides to their corresponding sulfoxides using urea hydrogen peroxide (UHP) as the oxidant at room temperature in air. Copyright © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

收藏

页码：385 / 389

页数：5

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