A new site-isolated acid-base bifunctional metal-organic framework for one-pot tandem reaction

被引：59

作者：

Lee, Yu-Ri ^{[1
]}

Chung, Young-Min ^{[2
]}

Ann, Wha-Seung ^{[1
]}

机构：

[1] Inha Univ, Dept Chem & Chem Engn, Inchon 402751, South Korea

[2] Kunsan Natl Univ, Dept Nano & Chem Engn, Kunsan 573701, Jeollabuk Do, South Korea

来源：

RSC ADVANCES | 2014年 / 4卷 / 44期

基金：

新加坡国家研究基金会;

关键词：

POST-SYNTHETIC MODIFICATION; CATALYSIS; LIGAND; AMINE; MOFS;

D O I：

10.1039/c4ra02683g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A highly porous and stable acid-base bifunctional metal-organic framework, MIL-101-NH2-SO3H, was prepared by direct solvothermal synthesis using two mixed (-NO2, -SO3H) terephthalate linkers followed by post-synthesis reduction to the NH2 form, which showed excellent performance for a one-pot tandem deacetalization-nitroaldol reaction.

引用

页码：23064 / 23067

页数：4

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