Pincer-Nickel-Catalyzed Cross-Coupling of Aryl Sulfamates with Arylzinc Chlorides

被引:14
作者
Tao, Jian-Long [1 ]
Wang, Zhong-Xia [1 ,2 ]
机构
[1] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China
[2] Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300072, Peoples R China
基金
中国国家自然科学基金;
关键词
Homogeneous catalysis; Cross-coupling; Pincer complexes; Nickel; Ligand design; Sulfamates; ORGANOZINC REAGENTS; GRIGNARD-REAGENTS; SUZUKI; ACTIVATION; PALLADIUM; MESYLATES; NI; AMINATION; CLEAVAGE; BONDS;
D O I
10.1002/ejoc.201500987
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The nickel N,N,N-pincer complex 2 was demonstrated to effectively catalyze the cross-coupling of aryl sulfamates with arylzinc chlorides under mild conditions. The reaction is suitable for a wide range of substrates, and tolerates various functional groups.
引用
收藏
页码:6534 / 6540
页数:7
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