A Convenient Method for the Preparation of N-Heterocyclic Bromophosphines: Excellent Precursors to the Corresponding N-Heterocyclic Phosphenium Salts

被引：47

作者：

Dube, Jonathan W. ^{[1
]}

Farrar, Gregory J. ^{[1
]}

Norton, Erin L. ^{[1
]}

Szekely, Kara L. S. ^{[1
]}

Cooper, Benjamin F. T. ^{[1
]}

Macdonald, Charles L. B. ^{[1
]}

机构：

[1] Univ Windsor, Dept Chem & Biochem, Windsor, ON N9B 3P4, Canada

来源：

ORGANOMETALLICS | 2009年 / 28卷 / 15期

关键词：

TRANSITION-METAL-COMPLEXES; MOLECULAR-STRUCTURE; PHOSPHORUS CATIONS; REDOX ROUTE; SELENIUM; IONS; CHEMISTRY; LIGANDS; CYCLOADDITION; COORDINATION;

D O I：

10.1021/om900420g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An in situ redox method is employed to prepare N-heterocyclic bromophosphines in good yield and purity. Such bromophosphines may be treated with a variety of bromide-abstracting reagents to produce the corresponding N-heterocyclic phosphenium salts in excellent yield.

引用

页码：4377 / 4384

页数：8

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