Excess enthalpies of (2,2,4-trimethylpentane plus cyclohexane plus dodecane) at the temperature 298.15 K

被引:0
|
作者
Wang, ZH [1 ]
Peng, DY [1 ]
Benson, GC [1 ]
Lu, BCY [1 ]
机构
[1] Univ Ottawa, Dept Chem Engn, Ottawa, ON K1N 6N5, Canada
来源
JOURNAL OF CHEMICAL THERMODYNAMICS | 2000年 / 32卷 / 02期
基金
加拿大自然科学与工程研究理事会;
关键词
excess enthalpy; ternary mixture; 2,2,4-trimethylpentane; cyclohexane; n-dodecane; Flory theory;
D O I
10.1006/jcht.1999.0600
中图分类号
O414.1 [热力学];
学科分类号
摘要
Measurements of excess molar enthalpies at the temperature 298.15 K, in a flow microcalorimeter are reported for the ternary mixture {x(1)(CH3)(3)CCH2CH(CH3)(2)(+) x(2)c-(CH2)(6) + (1 - x(1) - x(2))CH3(CH2)(10)CH3} A Smooth representation of the results is described and used to construct constant-enthalpy contours on a Roozeboom diagram. It is shown that useful estimates of the ternary enthalpies can be obtained from the Flory theory using only the physical properties of the components and their binary mixtures. (C) 2000 Academic Press.
引用
收藏
页码:261 / 267
页数:7
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