Synthesis and properties of a new member of the calixnaphthalene family:: A C2-Symmetrical endo-calix[4]naphthalene

被引：22

作者：

Chowdhury, S ^{[1
]}

Georghiou, PE ^{[1
]}

机构：

[1] Mem Univ Newfoundland, Dept Chem, St John, NF A1B 3X7, Canada

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2002年 / 67卷 / 19期

关键词：

D O I：

10.1021/jo026045v

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of a new endo-calix [4] naphthalene is described. The reaction sequence involves the cyclocon-densation of a key bisnaphthylmethane intermediate (8) with formaldehyde. This key intermediate (8) is formed using a modified Suzuki-Miyaura Pd-catalyzed cross-coupling reaction between bromomethylnaphthyl (6) and naphthylboronic acid (7), both of which can be derived from 2-hydroxynaphthoic acid.

引用

页码：6808 / 6811

页数：4

共 18 条

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