Performance test of new near-ambient-pressure XPS at Korean Basic Science Institute and its application to CO oxidation study on Pt3Ti polycrystalline surface

被引：19
作者：
Jeong, Changkil [1 ,2 ]
Yun, Hyungjoong [1 ]
Lee, Hyungcheol [2 ]
Muller, Sebastian [3 ]
Lee, Jouhahn [1 ]
Mun, Bongjin Simon [2 ]
机构：
[1] KOREA Basic Sci Inst, Adv Nanosurface Grp, Dajeon, South Korea
[2] Gwangju Inst Sci & Technol, Ertl Ctr Electrochem & Catalysis, Dept Phys & Photon Sci, Gwangju, South Korea
[3] Specs Surface Nano Anal GmbH, Dept Syst Engn, Berlin, Germany
来源：
CURRENT APPLIED PHYSICS | 2016年 / 16卷 / 01期
基金：
新加坡国家研究基金会;
关键词：
X-ray photoelectron spectroscopy; Near ambient pressure X-ray photoemission; CO oxidation; Pt alloys; Gas/solid interface; RAY PHOTOELECTRON-SPECTROSCOPY; INTERFACES; NANOPARTICLES; OXYGEN;
D O I：
10.1016/j.cap.2015.10.010
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
A performance test of near-ambient pressure X-ray photoelectron spectroscopy (NAP-XPS) at Korean Basic Science Institute (KBSI) in Daejeon, Korea is carried out. The NAP-XPS at KBSI is equipped with SPECS PHOIBOS 150 analyzer and 2-dimensional-delay line detector, which provides improved detection efficiency with 1-dimensional chemical imaging mode. The in-situ gas-pressure cell is designed to operate at pressure up to 25 mbar with differential pumping scheme. A micro-focused AlKa X-ray source is utilized as photon excitation source. The NAP-XPS is composed of two separate chambers, e.g. a main preparation chamber and a measurement chamber, which hold a low energy electron diffraction, a high pressure cell, an ion sputter gun, a multi-cell E-beam evaporators, and a four-axis manipulator with heating and cooling capability. As a test run of NAP-XPS, a CO oxidation experiment is carried out on Pt3Ti polycrystalline surface. During the active phase of CO oxidation, a clear formation of Ti oxide is found on surface, revealing the intriguing role of surface metal oxide in surface chemical reaction. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码：73 / 78
页数：6
相关论文
共 27 条
[1]   STRUCTURE AND CHEMISORPTIVE PROPERTIES OF THE PT3TI SURFACE [J].
BARDI, U ;
DAHLGREN, D ;
ROSS, PN .
JOURNAL OF CATALYSIS, 1986, 100 (01) :196-209
[2]   In situ x-ray photoelectron spectroscopy studies of gas-solid interfaces at near-ambient conditions [J].
Bluhm, Hendrik ;
Haevecker, Michael ;
Knop-Gericke, Axel ;
Kiskinova, Maya ;
Schloegl, Robert ;
Salmeron, Miquel .
MRS BULLETIN, 2007, 32 (12) :1022-1030
[3]   APPLICATION OF ELECTRON-SPECTROSCOPY TO SURFACE STUDIES [J].
BRUNDLE, CR .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY, 1974, 11 (01) :212-224
[4]   In Situ Oxidation Study of Pt(110) and Its Interaction with CO [J].
Butcher, Derek R. ;
Grass, Michael E. ;
Zeng, Zhenhua ;
Aksoy, Funda ;
Bluhm, Hendrik ;
Li, Wei-Xue ;
Mun, Bongjin S. ;
Somorjai, Gabor A. ;
Liu, Zhi .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (50) :20319-20325
[5]   PHOTOEMISSION-STUDIES OF A PT3TI POLYCRYSTALLINE SURFACE AFTER OXYGEN AND HYDROGEN TREATMENTS [J].
DAUSCHER, A ;
HILAIRE, L ;
SPIRLET, JC ;
MULLER, W ;
MAIRE, G .
SURFACE SCIENCE, 1988, 204 (1-2) :161-173
[6]  
Fadley C.S., 1978, ELECT SPECTROSCOPY, V2, P1
[7]   A Reactive Oxide Overlayer on Rhodium Nanoparticles during CO Oxidation and Its Size Dependence Studied by In Situ Ambient-Pressure X-ray Photoelectron Spectroscopy [J].
Grass, Michael E. ;
Zhang, Yawen ;
Butcher, Derek R. ;
Park, Jeong Y. ;
Li, Yimin ;
Bluhm, Hendrik ;
Bratlie, Kaitlin M. ;
Zhang, Tianfu ;
Somorjai, Gabor A. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (46) :8893-8896
[8]   AN XPS INVESTIGATION OF TIO2 THIN-FILMS ON POLYCRYSTALLINE PT [J].
GREENLIEF, CM ;
WHITE, JM ;
KO, CS ;
GORTE, RJ .
JOURNAL OF PHYSICAL CHEMISTRY, 1985, 89 (23) :5025-5028
[9]   HIGH-PRESSURE ELECTRON SPECTROMETER FOR SURFACE STUDIES [J].
JOYNER, RW ;
ROBERTS, MW ;
YATES, K .
SURFACE SCIENCE, 1979, 87 (02) :501-509
[10]   BINARY-ENCOUNTER-DIPOLE MODEL FOR ELECTRON-IMPACT IONIZATION [J].
KIM, YK ;
RUDD, ME .
PHYSICAL REVIEW A, 1994, 50 (05) :3954-3967
123