Highly selective and efficient reduction of CO2 to CO on cadmium electrodes derived from cadmium hydroxide

被引：21

作者：

Shi, Jinbiao ^{[1
,2
]}

Shao, Dan ^{[1
,2
]}

Zhang, Jianling ^{[1
,2
]}

Tan, Dongxing ^{[1
,2
]}

Tan, Xiuniang ^{[1
,2
]}

Zhang, Bingxing ^{[1
,2
]}

Han, Buxing ^{[1
,2
]}

Zhang, Fanyu ^{[1
,2
]}

Liu, Lifei ^{[1
,2
]}

Cheng, Xiuyan ^{[1
,2
]}

机构：

[1] Chinese Acad Sci, Inst Chem, CAS Key Lab Colloid Interface & Chem Thermodynam, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China

[2] Univ Chinese Acad Sci, Sch Chem & Chem Engn, Beijing 100049, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 43期

基金：

中国国家自然科学基金;

关键词：

ELECTROCHEMICAL REDUCTION; CARBON-DIOXIDE; ELECTROCATALYTIC REDUCTION; CONVERSION; TIN;

D O I：

10.1039/c8cc02055h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A non-noble cadmium electrode was synthesized via an electrolysis strategy, which can electroreduce carbon dioxide into carbon monoxide with high selectivity and efficiency. The partial current density for CO can reach up to 59.0 mA cm(-2) at a Faradaic efficiency of 99.2% using 1-butyl-3-methylimidazolium hexafluorophosphate/acetonitrile as the electrolyte.

引用

页码：5450 / 5453

页数：4

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