Isothermal Crystallization Behavior of Poly(L-lactic acid)/Organo-Montmorillonite Composites

被引：0
作者：
Cai, Yan-Hua [1 ]
Miao, Ya-Wei [1 ]
Wang, Zheng-Yong [1 ]
机构：
[1] Chongqing Univ Arts & Sci, Chongqing Key Lab Environm Mat & Remediat Technol, Chongqing 402160, Peoples R China
来源：
ASIAN JOURNAL OF CHEMISTRY | 2014年 / 26卷 / 04期
基金：
中国博士后科学基金;
关键词：
Montmorillonite; Crystallization time; Poly(L-lactic acid); Crystallization kinetic; MICROSTRUCTURE; NANOCOMPOSITES; KINETICS; HYBRID; ACID); CLAY;
D O I：
10.14233/ajchem.2014.16423
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In this research, organo-montmorillonite (OMMT) was synthesized by ion exchange technology, Then the poly(L-lactic acid)(PLLA)/OMMT composites were fabricated using melt blending and hot-press forming. The isothermal crystallization behavior of PLLA/OMMT composites was investigated in detail and isothermal crystllization behavior was affected by crystallization temperature and organomontmorillonite content. Compared to the neat poly(L-lactic acid), the half-time of poly(L-lactic acid) with 5 % organo-montmorillonite decreases from 2991.5s to 327s. and the kinetic of isothermal crystallization of PLLA/OMMT was described by Avrami theory and the results showed that PLLA/OMMT composite had complicated nucleation mechanism.
引用
收藏
页码：1237 / 1240
页数：4
相关论文
共 17 条
  • [11] Regioselective -Bromination of Aralkyl Ketones Using N-Bromosuccinimide in the Presence of Montmorillonite K-10 Clay: A Simple and Efficient Method
    Mohan, Reddy Bodireddy
    Reddy, N. C. Gangi
    [J]. SYNTHETIC COMMUNICATIONS, 2013, 43 (19) : 2603 - 2614
  • [12] Preparation of cationic exchange membranes based on organo-montmorillonite/poly(vinylidene fluoride) by two-step chemically induced grafting method
    Tian, Bo
    Li, Haixiao
    Zhang, Wei
    Li, Sanxi
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 2013, 130 (04) : 2753 - 2763
  • [13] Isothermal and non-isothermal crystallization behavior of poly(L-lactic acid): Effects of stereocomplex as nucleating agent
    Tsuji, Hideto
    Takai, Hiroki
    Saha, Swapan Kumar
    [J]. POLYMER, 2006, 47 (11) : 3826 - 3837
  • [14] Multi-scale micro-structure generation strategy for up-scaling transport in clays
    Tyagi, Manav
    Gimmi, Thomas
    Churakov, Sergey V.
    [J]. ADVANCES IN WATER RESOURCES, 2013, 59 : 181 - 195
  • [15] Nonisothermal crystallization kinetics of polyoxymethylene/montmorillonite nanocomposite
    Xu, W
    Ge, M
    He, P
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 2001, 82 (09) : 2281 - 2289
  • [16] Biodegradable poly(L-lactide)/poly(ε-caprolactone)-modified montmorillonite nanocomposites:: Preparation and characterization
    Yu, Zhenyang
    Yin, Jingbo
    Yan, Shifeng
    Xie, Yongtao
    Ma, Jia
    Chen, Xuesi
    [J]. POLYMER, 2007, 48 (21) : 6439 - 6447
  • [17] Preparation and properties of unsaturated polyester-montmorillonite intercalated hybrid
    Zhang, YH
    Cai, QY
    Jiang, ZJ
    Gong, KC
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 2004, 92 (03) : 2038 - 2044
12